Self-assembly of a fluorescent chiral zinc(II) complex that leads to supramolecular helices

被引：97

作者：

Prabhakar, M ^{[1
]}

Zacharias, PS ^{[1
]}

Das, SK ^{[1
]}

机构：

[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 08期

关键词：

D O I：

10.1021/ic048236h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chiral Zn(II) complex [ZnLCl2], 1 {L = 4-methyl-2,6-di[(S)(+)-1-phenylethyliminomethyl] phenol}, self-assembles via C-(HCl)-Cl-... hydrogen bonding into supramolecular helices. Complex 1 exhibits emission in solution at room temperature in the visible range. Crystal data for 1: orthorhombic space group P2(1)2(1)2, a 9.614(2) angstrom, b = 13.825(3) angstrom, c = 18.667(3) angstrom, V = 2481.1(8) angstrom(3), Z = 4.

引用

页码：2585 / 2587

页数：3

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