The unprecedented transformation of a sterically crowded cyclopalladated secondary benzylamine including (sp3)C-C(sp3) bond activation under mild conditions

被引：8

作者：

Dunina, VV ^{[1
]}

Golovan, EB ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 01期

基金：

俄罗斯基础研究基金会; 以色列科学基金会;

关键词：

cyclopalladation; palladium complexes; benzylamine complexes; C-C bond activation;

D O I：

10.1016/S1387-7003(97)00005-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An unusual process of palladium mediated cleavage of an (sp(3))C-C(sp(3)) bond between two non-activated carbon atoms in a sterically crowded secondary benzylamine is discovered. It includes the conversion of cyclopalladated N-methyl-alpha-tert-butplbenzylamine formed at the first stage into the ortho-palladated N-methylbenzylidenamine. (C) 1998 Elsevier Science S.A.

引用

页码：12 / 14

页数：3

共 18 条

[1] INTERLIGAND C-C SIGMA-BOND BREAKING AND REPAIR IN A STAPLED BIS(PHTHALOCYANINATO)TITANIUM COMPLEX - SYNTHESIS, CHARACTERIZATION, AND ELECTRICAL-CONDUCTIVITY PROPERTIES OF OXIDATION-PRODUCTS OF BIS(PHTHALOCYANINATO)TITANIUM(IV) AND BIS(PHTHALOCYANINATO)TIN(IV) AND X-RAY CRYSTAL-STRUCTURE OF [PC2TI](I3)0.66 [J].

CAPOBIANCHI, A ;

ERCOLANI, C ;

PAOLETTI, AM ;

PENNESI, G ;

ROSSI, G ;

CHIESIVILLA, A ;

RIZZOLI, C .

INORGANIC CHEMISTRY, 1993, 32 (21) :4605-4611

[2] THE ORGANOMETALLIC CHEMISTRY OF ALKANES [J].

CRABTREE, RH .

CHEMICAL REVIEWS, 1985, 85 (04) :245-269

[3] COMPARISON OF 8-METHYLQUINOLINE AND BENZO[H]QUINOLINE COMPLEXES OF PALLADIUM(II) WITH THOSE OF RELATED LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA(BENZO[H]QUINOLINE)[2-(DIMETHYLAMINOMETHYL)PHENYL-N]PALLADIUM(II) PERCHLORATE [J].

DEEMING, AJ ;

ROTHWELL, IP ;

HURSTHOUSE, MB ;

NEW, L .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (11) :1490-1496

[4] GENERAL-PRINCIPLES AND CHARACTERISTICS OF CYCLOPALLADATION [J].

DUNINA, VV ;

ZALEVSKAYA, OA ;

POTAPOV, VM .

USPEKHI KHIMII, 1988, 57 (03) :434-473

[5]

DUNINA VV, 1993, METALLOORG KHIM, V6, P36

[6]

DUNINA VV, UNPUB

[7] FORMATION OF AN OXALATE-BRIDGED PHENYLPALLADIUM(II) COMPLEX FROM PHENYLGLYOXYLIC ACID AND PALLADIUM ACETATE - SYNTHESIS AND STRUCTURE OF [(BU2S)(PH)PD(MU-C2O4)PD(PH) (SBU2)] [J].

KRAMER, R ;

POLBORN, K ;

BECK, W .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 441 (02) :333-337

[8] CARBON-CARBON BOND-CLEAVAGE IN ORGANOCOBALT COMPLEXES WITH AGOSTIC C...H...CO BONDING [J].

NICHOLLS, JC ;

SPENCER, JL .

ORGANOMETALLICS, 1994, 13 (05) :1781-1787

[9] ORTHO METALATION REACTIONS OF N-PHENYLBENZALDIMINE AND ITS RELATED COMPOUNDS BY PALLADIUM(II) ACETATE [J].

ONOUE, H ;

MORITANI, I .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 43 (02) :431-&

[10] CATALYTIC HYDROGENOLYSIS OF AN ARYL-ARYL CARBON-CARBON BOND WITH A RHODIUM COMPLEX [J].

PERTHUISOT, C ;

JONES, WD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (08) :3647-3648

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