multicomponent carbonylative Suzuki reaction: novel practical synthesis of unsymmetric aryl ketones

被引：46

作者：

Zheng, ShuZhan

Xu, Liwen

Xia, ChunGu ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Beijing 100039, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

[3] Hangzhou Teachers Coll, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 310012, Peoples R China

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2007年 / 21卷 / 09期

关键词：

carbonylative Suzuki reaction; N-Heterocyclic carbene; palladium; unsymmetric ketone;

D O I：

10.1002/aoc.1289

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Highly efficient and chemoselective N-heterocyclic carbene palladium complexes-catalyzed multicomponent carbonyltive Suzuki reaction with sodium tetraphertylborate used as phertylating reagent has been demonstrated in this article. Both electron-rich and electron-deficient aryl iodides gave unsymmetric aryl ketones in excellent yields. Copyright (c) 2007 John Wiley & Sons, Ltd.

引用

页码：772 / 776

页数：5

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