Stereoselective synthesis of 1,2-aminoalcohols by [2,3]-Wittig rearrangements

被引：37

作者：

Barbazanges, Marion ^{[1
]}

Meyer, Christophe ^{[1
]}

Cossy, Janine ^{[1
]}

机构：

[1] ESPCI, CNRS, Chim Organ Lab, F-75231 Paris, France

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 17期

关键词：

D O I：

10.1021/ol0711725

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[2,3]-Wittig rearrangements of (E)-3-aza-allylic alcohol derivatives can provide access to functionalized 1,2-aminoalcohols with high syn or anti diastereoselectivity depending on the anionic stabilizing group (amide or alkyne).

引用

页码：3245 / 3248

页数：4

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