Tuning the crystal morphology and size of zeolitic imidazolate framework-8 in aqueous solution by surfactants

被引:432
作者
Pan, Yichang [1 ]
Heryadi, Dodi [1 ]
Zhou, Feng [2 ]
Zhao, Lan [1 ]
Lestari, Gabriella [1 ]
Su, Haibin [2 ]
Lai, Zhiping [1 ]
机构
[1] King Abdullah Univ Sci & Technol, Div Chem & Life Sci & Engn, Adv Membranes & Porous Mat Ctr, Thuwal 239556900, Saudi Arabia
[2] Nanyang Technol Univ, Div Mat Sci, Singapore 639798, Singapore
关键词
METAL-ORGANIC FRAMEWORKS; POROUS COORDINATION POLYMER; NANOCRYSTALS; GROWTH; TEMPERATURE; SEPARATION; DESIGN;
D O I
10.1039/c1ce05780d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Herein we report a facile synthesis method using surfactant cetyltrimethylammonium bromide (CTAB) as a capping agent for controlling the crystal size and morphology of zeolitic imidazolate framework-8 (ZIF-8) crystals in aqueous systems. The particle sizes can be precisely adjusted from ca. 100 nm to 4 mu m, and the morphology can be changed from truncated cubic to rhombic dodecahedron.
引用
收藏
页码:6937 / 6940
页数:4
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