Artificial Photosynthesis for Sustainable Fuel and Chemical Production

被引:583
作者
Kim, Dohyung [3 ]
Sakimoto, Kelsey K. [1 ]
Hong, Dachao [1 ]
Yang, Peidong [1 ,2 ]
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Kavli Energy Nanosci Inst, Berkeley, CA 94720 USA
[3] Univ Calif Berkeley, Dept Mat Sci & Engn, Berkeley, CA 94720 USA
基金
美国国家科学基金会;
关键词
artificial photosynthesis; carbon dioxide reduction; heterogeneous catalysis; sustainable chemistry; water splitting; CARBON-DIOXIDE REDUCTION; ATOMIC LAYER DEPOSITION; CO2; REDUCTION; ELECTROCHEMICAL REDUCTION; HYDROGEN-PEROXIDE; METHANOL SYNTHESIS; AMMONIA-SYNTHESIS; SURFACTANT-FREE; WATER; CATALYSTS;
D O I
10.1002/anie.201409116
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The apparent incongruity between the increasing consumption of fuels and chemicals and the finite amount of resources has led us to seek means to maintain the sustainability of our society. Artificial photosynthesis, which utilizes sunlight to create high-value chemicals from abundant resources, is considered as the most promising and viable method. This Minireview describes the progress and challenges in the field of artificial photosynthesis in terms of its key components: developments in photoelectrochemical water splitting and recent progress in electrochemical CO2 reduction. Advances in catalysis, concerning the use of renewable hydrogen as a feedstock for major chemical production, are outlined to shed light on the ultimate role of artificial photosynthesis in achieving sustainable chemistry.
引用
收藏
页码:3259 / 3266
页数:8
相关论文
共 72 条
[1]  
[Anonymous], 2013, International Energy Outlook 2013
[2]   Robust carbon dioxide reduction on molybdenum disulphide edges [J].
Asadi, Mohammad ;
Kumar, Bijandra ;
Behranginia, Amirhossein ;
Rosen, Brian A. ;
Baskin, Artem ;
Repnin, Nikita ;
Pisasale, Davide ;
Phillips, Patrick ;
Zhu, Wei ;
Haasch, Richard ;
Klie, Robert F. ;
Kral, Petr ;
Abiade, Jeremiah ;
Salehi-Khojin, Amin .
NATURE COMMUNICATIONS, 2014, 5
[3]  
Behrens M, 2012, SCIENCE, V336, P893, DOI [10.1126/science.1219831, 10.1126/science.12198331]
[4]   Comparing Photosynthetic and Photovoltaic Efficiencies and Recognizing the Potential for Improvement [J].
Blankenship, Robert E. ;
Tiede, David M. ;
Barber, James ;
Brudvig, Gary W. ;
Fleming, Graham ;
Ghirardi, Maria ;
Gunner, M. R. ;
Junge, Wolfgang ;
Kramer, David M. ;
Melis, Anastasios ;
Moore, Thomas A. ;
Moser, Christopher C. ;
Nocera, Daniel G. ;
Nozik, Arthur J. ;
Ort, Donald R. ;
Parson, William W. ;
Prince, Roger C. ;
Sayre, Richard T. .
SCIENCE, 2011, 332 (6031) :805-809
[5]   Photoelectrochemical Hydrogen Evolution Using Si Microwire Arrays [J].
Boettcher, Shannon W. ;
Warren, Emily L. ;
Putnam, Morgan C. ;
Santori, Elizabeth A. ;
Turner-Evans, Daniel ;
Kelzenberg, Michael D. ;
Walter, Michael G. ;
McKone, James R. ;
Brunschwig, Bruce S. ;
Atwater, Harry A. ;
Lewis, Nathan S. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (05) :1216-1219
[6]   HYDROCARBONS FROM METHANOL [J].
CHANG, CD .
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1983, 25 (01) :1-118
[7]   New developments in hydrogenation catalysis particularly in synthesis of fine and intermediate chemicals [J].
Chen, B ;
Dingerdissen, U ;
Krauter, JGE ;
Rotgerink, HGJL ;
Möbus, K ;
Ostgard, DJ ;
Panster, P ;
Riermeier, TH ;
Seebald, S ;
Tacke, T ;
Trauthwein, H .
APPLIED CATALYSIS A-GENERAL, 2005, 280 (01) :17-46
[8]  
Chen YW, 2011, NAT MATER, V10, P539, DOI [10.1038/NMAT3047, 10.1038/nmat3047]
[9]   Aqueous CO2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles [J].
Chen, Yihong ;
Li, Christina W. ;
Kanan, Matthew W. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (49) :19969-19972
[10]   Tin Oxide Dependence of the CO2 Reduction Efficiency on Tin Electrodes and Enhanced Activity for Tin/Tin Oxide Thin-Film Catalysts [J].
Chen, Yihong ;
Kanan, Matthew W. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (04) :1986-1989