Monolayers of polyethilenimine on flat glass: a versatile platform for cations coordination and nanoparticles grafting in the preparation of antibacterial surfaces

被引:44
作者
Dacarro, Giacomo [1 ]
Cucca, Lucia [2 ]
Grisoli, Pietro [3 ]
Pallavicini, Piersandro [4 ]
Patrini, Maddalena [1 ]
Taglietti, Angelo [4 ]
机构
[1] Univ Pavia, Dipartimento Fis A Volta, I-27100 Pavia, Italy
[2] Univ Pavia, Dipartimento Chim, Analyt Chem Sect, I-27100 Pavia, Italy
[3] Univ Pavia, Dipartimento Sci Farmacosez Farmacol Sperimentale, I-27100 Pavia, Italy
[4] Univ Pavia, Dipartimento Chim, Inorgan Nanochem Lab, I-27100 Pavia, Italy
关键词
SELF-ASSEMBLED MONOLAYERS; SILVER NANOPARTICLES; MESOPOROUS SILICA; PLASMON RESONANCE; THIN-FILMS; METAL-IONS; GOLD; POLYETHYLENIMINE; NANODISKS; REMOVAL;
D O I
10.1039/c1dt11373a
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A polyethylenimine (PEI) self-assembled monolayer (SAM) is prepared, capable of complexing silver and copper cations and of anchoring silver nanoparticles, exerting antibacterial activity against Escherichia coli and Staphylococcus aureus. Functionalized glassy surfaces have been fully characterized through spectroscopic techniques (UV-Vis spectroscopy, spectroscopic ellipsometry), atomic force microscopy imaging and quantitative Ag and Cu analysis (ICP optical emission spectroscopy).
引用
收藏
页码:2456 / 2463
页数:8
相关论文
共 59 条
[1]   5-COORDINATE COPPER(II) COMPLEXES - SYNTHESIS AND PROPERTIES OF [CU(TREN)L]2+ CATIONS [J].
ALBERTIN, G ;
BORDIGNON, E ;
ORIO, AA .
INORGANIC CHEMISTRY, 1975, 14 (06) :1411-1413
[2]   Synthesis, Characterization and Antibacterial Activity against Gram Positive and Gram Negative Bacteria of Biomimetically Coated Silver Nanoparticles [J].
Amato, Elvio ;
Diaz-Fernandez, Yuri A. ;
Taglietti, Angelo ;
Pallavicini, Piersandro ;
Pasotti, Luca ;
Cucca, Lucia ;
Milanese, Chiara ;
Grisoli, Pietro ;
Dacarro, Cesare ;
Fernandez-Hechavarria, Jose M. ;
Necchi, Vittorio .
LANGMUIR, 2011, 27 (15) :9165-9173
[3]   Novel one-step synthesis of amine-stabilized aqueous colloidal gold nanoparticles [J].
Aslam, M ;
Fu, L ;
Su, M ;
Vijayamohanan, K ;
Dravid, VP .
JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (12) :1795-1797
[4]   Photopatterning of Cell-Adhesive-Modified Poly(ethyleneimine) for Guided Neuronal Growth [J].
Baek, Nam Seob ;
Lee, Ji-Hyun ;
Kim, Yong Hee ;
Lee, Bong Joon ;
Kim, Gook Hwa ;
Kim, Ik-Hyun ;
Chung, Myung-Ae ;
Jung, Sang-Don .
LANGMUIR, 2011, 27 (06) :2717-2722
[5]   A simple approach to sensor discovery and fabrication on self-assembled monolayers on glass [J].
Basabe-Desmonts, L ;
Beld, J ;
Zimmerman, RS ;
Hernando, J ;
Mela, P ;
García-Parajó, MF ;
van Hulst, NF ;
van den Berg, A ;
Reinhoudt, DN ;
Crego-Calama, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (23) :7293-7299
[6]   THERMODYNAMICS OF COMPLEX-FORMATION IN DIMETHYL-SULFOXIDE - SILVER(I) WITH QUADRIDENTATE POLYAMINES [J].
CASSOL, A ;
DIBERNARDO, P ;
ZANONATO, PL ;
PORTANOVA, R ;
TOLAZZI, M ;
TOMAT, G .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (16) :2841-2845
[7]  
CHAUFER B, 1988, Nuclear and Chemical Waste Management, V8, P175, DOI 10.1016/0191-815X(88)90025-3
[8]   Effects of alkylated polyethylenimines on the formation of gold nanoplates [J].
Chen, Chi-Chang ;
Hsu, Chyuan-Heng ;
Kuo, Ping-Lin .
LANGMUIR, 2007, 23 (12) :6801-6806
[9]   Silver nanodisks: Synthesis, characterization, and self-assembly [J].
Chen, SH ;
Fan, ZY ;
Carroll, DL .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (42) :10777-10781
[10]   Thermodynamics of complex formation of silver(I), cadmium(II) and cobalt(II) with open-chain polyamines in dimethyl sulfoxide and molecular dioxygen binding to cobalt(II) complexes [J].
Comuzzi, C ;
Melchior, A ;
Polese, P ;
Portanova, R ;
Tolazzi, M .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (10) :1948-1955