Continuous flow hydrogenation using polysilane-supported palladium/alumina hybrid catalysts

被引：42

作者：

Oyamada, Hidekazu

Naito, Takeshi

Kobayashi, Shu ^{[1
]}

机构：

[1] Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 7卷

基金：

日本学术振兴会;

关键词：

flow chemistry; hydrogenation; polysilane; palladium; reduction; REACTOR; NANOPARTICLES; REDUCTION; DEVICE;

D O I：

10.3762/bjoc.7.83

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Continuous flow systems for hydrogenation using polysilane-supported palladium/alumina (Pd/(PSi-Al(2)O(3))) hybrid catalysts were developed. Our original Pd/(PSi-Al(2)O(3)) catalysts were used successfully in these systems and the hydrogenation of unsaturated C-C bonds and a nitro group, deprotection of a carbobenzyloxy (Cbz) group, and a dehalogenation reaction proceeded smoothly. The catalyst retained high activity for at least 8 h under neat conditions.

引用

收藏

页码：735 / 739

页数：5

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