Experimental Characterization and Numerical Modeling of the Corrosion Effect on the Mechanical Properties of the Biodegradable Magnesium Alloy WE43 for Orthopedic Applications

被引:3
|
作者
Saconi, Felipe [1 ]
Diaz, Geraldine Hincapie [1 ]
Vieira, Andre Costa [2 ]
Ribeiro, Marcelo Leite [1 ]
机构
[1] Univ Sao Paulo, Sao Carlos Sch Engn, Aeronaut Engn Dept, BR-13563500 Sao Carlos, SP, Brazil
[2] Univ Beira Interior, Ctr Mech & Aerosp Sci & Technol C MAST UBI, R Marques DAvila & Bolama, P-6201001 Covilha, Portugal
关键词
biodegradable magnesium alloy WE43; numerical simulation; continuum damage mechanics; corrosion; finite elements method; PITTING CORROSION; IMPLANTS; INTEGRITY; STRENGTH; SCREWS;
D O I
10.3390/ma15207164
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Computational modeling plays an important role in the design of orthopedic implants. In the case of biodegradable magnesium alloys, a modeling approach is required to predict the effects of degradation on the implant's capacity to provide the desired stabilization of fractured bones. In the present work, a numerical corrosion model is implemented to predict the effects of biodegradation on the structural integrity of temporary trauma implants. A non-local average pitting corrosion model is calibrated based on experimental data collected from in vitro degradation experiments and mechanical testing of magnesium WE43 alloy specimens at different degradation stages. The localized corrosion (pitting) model was implemented by developing a user material subroutine (VUMAT) with the program Abaqus (R)/Explicit. In order to accurately capture both the linear mechanical reduction in specimen resistance, as well as the non-linear corrosion behavior of magnesium WE43 observed experimentally, the corrosion model was extended by employing a variable corrosion kinetic parameter, which is time-dependent. The corrosion model was applied to a validated case study involving the pull-out test of orthopedic screws and was able to capture the expected loss of screw pull-out force due to corrosion. The proposed numerical model proved to be an efficient tool in the evaluation of the structural integrity of biodegradable magnesium alloys and bone-implant assembly and can be used in future works in the design optimization and pre-validation of orthopedic implants.
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页数:20
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