Synthesis of the ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}](Ru→B)8 and [Ru(CO)(CNR){B(mt)3}](Ru→B)8 (mt = methimazolyl, R = tBu, C6H3Me2-2,6, C6H2Me3-2,4,6)

被引：73

作者：

Crossley, Ian R. ^{[1
]}

Foreman, Mark R. St. -J. ^{[2
]}

Hill, Anthony F. ^{[1
]}

Owen, Gareth R. ^{[2
]}

White, Andrew J. P. ^{[2
]}

Williams, David J. ^{[2
]}

Willis, Anthony C. ^{[1
]}

机构：

[1] Australian Natl Univ, Res Sch Chem, Inst Adv Studies, Canberra, ACT, Australia

[2] Imperial Coll London, Dept Chem, London SW7 2AZ, England

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 03期

关键词：

D O I：

10.1021/om7008777

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Ru(CH=CH2)Cl(CS)(PPh3)(2)] with Na[HB(mt)(3)] (mt = methimazolyl) provides the ruthenaboratrane [Ru(CS)(PPh3){B(mt)(3)}]. The reaction of [Ru(CO)(PPh3){B(mt)3}] with CO to provide [Ru(CO)(2){B(mt)(3)}] is reversible, while the phosphine-free ruthenaboratranes [Ru(CO)(CNR){B(mt(3))}] (R = Bu-t, C6H3Me2-2,6, C6H2Me3-2,4,6) form irreversibly upon addition of isonitriles (CNR) to [Ru(CO)(PPh3){B(mt)(3)}]. The crystal structures of the ruthenaboratranes [Ru(CS)(PPh3){B(mt)(3)}], [Ru(CO)((CNBu)-Bu-t)({B(mt)(3)}], and [Ru(CO)(CNC6H2Me3-2,4,6){B(mt)(3)}] are reported.

引用

页码：381 / 386

页数：6

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