Development of Preformed Pd Catalysts for Cross-Coupling Reactions, Beyond the 2010 Nobel Prize

被引：384

作者：

Li, Hongbo ^{[1
]}

Seechurn, Carin C. C. Johansson ^{[2
]}

Colacot, Thomas J. ^{[1
]}

机构：

[1] Johnson Matthey Catalysis & Chiral Technol, W Deptford, NJ 08066 USA

[2] Johnson Matthey Catalysis & Chiral Technol, Royston SG8 5HE, Herts, England

来源：

ACS CATALYSIS | 2012年 / 2卷 / 06期

关键词：

cross-coupling; palladium; precatalysts; N-HETEROCYCLIC-CARBENE; C-O BOND; ACTIVE PALLADIUM CATALYSTS; AIR-STABLE CATALYSTS; ARYL CHLORIDES; ROOM-TEMPERATURE; DIRECT ARYLATION; ALPHA-ARYLATION; GENERAL-METHOD; HECK REACTIONS;

D O I：

10.1021/cs300082f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Strategies for the development of Pd catalysts based on utilization of L2Pd and LPd species, beyond the contributions of the 2010 Nobel Laureates Richard Heck, Ei-ichi Negishi, and Akira Suzuki, along with their contemporaries, are reviewed. These well-defined, preformed Pd catalysts improve the selectivity and activity of selected cross-coupling reactions by reducing the metal loading and the ligand-to-metal ratios. This review describes predominantly the development of Pd precatalysts over the last 10 years and highlights the benefits often observed when using well-defined preformed catalysts relative to those generated in situ.

引用

页码：1147 / 1164

页数：18

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