Development of Preformed Pd Catalysts for Cross-Coupling Reactions, Beyond the 2010 Nobel Prize

被引：384

作者：

Li, Hongbo ^{[1
]}

Seechurn, Carin C. C. Johansson ^{[2
]}

Colacot, Thomas J. ^{[1
]}

机构：

[1] Johnson Matthey Catalysis & Chiral Technol, W Deptford, NJ 08066 USA

[2] Johnson Matthey Catalysis & Chiral Technol, Royston SG8 5HE, Herts, England

来源：

ACS CATALYSIS | 2012年 / 2卷 / 06期

关键词：

cross-coupling; palladium; precatalysts; N-HETEROCYCLIC-CARBENE; C-O BOND; ACTIVE PALLADIUM CATALYSTS; AIR-STABLE CATALYSTS; ARYL CHLORIDES; ROOM-TEMPERATURE; DIRECT ARYLATION; ALPHA-ARYLATION; GENERAL-METHOD; HECK REACTIONS;

D O I：

10.1021/cs300082f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Strategies for the development of Pd catalysts based on utilization of L2Pd and LPd species, beyond the contributions of the 2010 Nobel Laureates Richard Heck, Ei-ichi Negishi, and Akira Suzuki, along with their contemporaries, are reviewed. These well-defined, preformed Pd catalysts improve the selectivity and activity of selected cross-coupling reactions by reducing the metal loading and the ligand-to-metal ratios. This review describes predominantly the development of Pd precatalysts over the last 10 years and highlights the benefits often observed when using well-defined preformed catalysts relative to those generated in situ.

引用

页码：1147 / 1164

页数：18

共 50 条

[21] Pd-catalyzed Suzuki cross-coupling reactions of glycerol arylboronic esters
Nichele, Tatiana Z.
Favero, Cristiano
Monteiro, Adriano L.
CATALYSIS COMMUNICATIONS, 2009, 10 (05) : 693 - 696
[22] Development and Industrialization of Efficient Cross-Coupling Reactions
Eguchi, Hisao
Nishiyama, Masakazu
Ishikawa, Shin-ichi
Soga, Shin-ichi
Koie, Yasuyuki
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2012, 70 (09) : 937 - 946
[23] Pd/NHC-catalyzed cross-coupling reactions of nitroarenes
Kashihara, Myuto
Zhong, Rong-Lin
Semba, Kazuhiko
Sakaki, Shigeyoshi
Nakao, Yoshiaki
CHEMICAL COMMUNICATIONS, 2019, 55 (63) : 9291 - 9294
[24] Total Synthesis of Asparenydiol by Two Sonogashira Cross-Coupling Reactions Promoted by Supported Pd and Cu Catalysts
Casotti, Gianluca
Fusini, Graziano
Ferreri, Matteo
Pardini, Luca Fidia
Evangelisti, Claudio
Angelici, Gaetano
Carpita, Adriano
SYNTHESIS-STUTTGART, 2020, 52 (12): : 1795 - 1803
[25] The Role of PEG on Pd- and Cu-Catalyzed Cross-Coupling Reactions
Pires, Marina J. D.
Purificacao, Sara I.
Sofia Santos, A.
Marques, M. Manuel B.
SYNTHESIS-STUTTGART, 2017, 49 (11): : 2337 - 2350
[26] Novel palladium imidazole catalysts for Suzuki cross-coupling reactions
Mathews, CJ
Smith, PJ
Welton, T
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 206 (1-2) : 77 - 82
[27] Simplifying Iron-Phosphine Catalysts for Cross-Coupling Reactions
Bedford, Robin B.
Carter, Emma
Cogswell, Paul M.
Gower, Nicholas J.
Haddow, Mairi F.
Harvey, Jeremy N.
Murphy, Damien M.
Neeve, Emily C.
Nunn, Joshua
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (04) : 1285 - 1288
[28] Use of Nanoparticles as Catalysts in Organic Synthesis - Cross-coupling Reactions
Sydnes, Magne O.
CURRENT ORGANIC CHEMISTRY, 2014, 18 (03) : 312 - 326
[29] Pd-catalyzed cross-coupling reactions of alkyl halides
Kambe, Nobuaki
Iwasaki, Takanori
Terao, Jun
CHEMICAL SOCIETY REVIEWS, 2011, 40 (10) : 4937 - 4947
[30] Palladium-Catalyzed Cross-Coupling Reactions of Cyclopropanols
Rosa, David
Nikolaev, Andrei
Nithiy, Nisha
Orellana, Arturo
SYNLETT, 2015, 26 (04) : 441 - 448

← 1 2 3 4 5 →