Development of Preformed Pd Catalysts for Cross-Coupling Reactions, Beyond the 2010 Nobel Prize

被引：384
|
作者：
Li, Hongbo [1 ]
Seechurn, Carin C. C. Johansson [2 ]
Colacot, Thomas J. [1 ]
机构：
[1] Johnson Matthey Catalysis & Chiral Technol, W Deptford, NJ 08066 USA
[2] Johnson Matthey Catalysis & Chiral Technol, Royston SG8 5HE, Herts, England
来源：
ACS CATALYSIS | 2012年 / 2卷 / 06期
关键词：
cross-coupling; palladium; precatalysts; N-HETEROCYCLIC-CARBENE; C-O BOND; ACTIVE PALLADIUM CATALYSTS; AIR-STABLE CATALYSTS; ARYL CHLORIDES; ROOM-TEMPERATURE; DIRECT ARYLATION; ALPHA-ARYLATION; GENERAL-METHOD; HECK REACTIONS;
D O I：
10.1021/cs300082f
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Strategies for the development of Pd catalysts based on utilization of L2Pd and LPd species, beyond the contributions of the 2010 Nobel Laureates Richard Heck, Ei-ichi Negishi, and Akira Suzuki, along with their contemporaries, are reviewed. These well-defined, preformed Pd catalysts improve the selectivity and activity of selected cross-coupling reactions by reducing the metal loading and the ligand-to-metal ratios. This review describes predominantly the development of Pd precatalysts over the last 10 years and highlights the benefits often observed when using well-defined preformed catalysts relative to those generated in situ.
引用
收藏
页码：1147 / 1164
页数：18
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