Studies on synthesis of methyl glycolate and methyl methoxy acetate from the coupling of formaldehyde and methyl formate

被引：4

作者：

He, DH ^{[1
]}

Huang, WG ^{[1
]}

Liu, JY ^{[1
]}

Zhou, MX ^{[1
]}

Zhu, QM ^{[1
]}

机构：

[1] Tsing Hua Univ, State Key Lab Chem Technol C1, Beijing, Peoples R China

来源：

KOREAN JOURNAL OF CHEMICAL ENGINEERING | 1998年 / 15卷 / 05期

关键词：

methyl glycolate; methyl methoxy acetate; coupling; formaldehyde; methyl formate;

D O I：

10.1007/BF02707109

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic performance of various acids in the coupling reaction of formaldehyde and methyl formate to produce methyl glycolate and methyl methoxy acetate has been studied. The influence of reaction conditions, such as catalyst amount, reaction temperature, reaction time, and molar ratio of formaldehyde to methyl formate, has also been investigated. The results showed that the acid strength had great influence on the reaction, namely, stronger acids had higher activities. It was also found that the reaction temperature and time had significant effect on the reaction, and the preferable conditions were quite different as different acids were used.

引用

页码：556 / 558

页数：3