Polymerization of acrylonitrile with organolanthanides as single-component catalysts

被引：0
|
作者：
Ying, LQ [1 ]
Ba, XW [1 ]
Zhao, YY [1 ]
Li, G [1 ]
Tang, T [1 ]
Jin, YT [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
来源：
CHINESE JOURNAL OF POLYMER SCIENCE | 2001年 / 19卷 / 01期
关键词：
acrylonitrile; organolanthanide; polymerization;
D O I：
暂无
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Ind(2)Y(mu -Et)(2)AlEt2 and Ind(2)LnN(i-Pr)(2) (Ln = Y, Yb) were used as a single-component catalyst for the polymerization of acrylonitrile (AN) respectively. The regularity of polymerization of AN and stereoregularity of polyacrylonitrile (PAN) were also studied in both cases. Both catalysts can produce PAN with molecular weight from 10,000 to 30,000. In addition, the catalytic activity and molecular weights were increased by the addition of PhONa.
引用
收藏
页码：89 / 91
页数：3
相关论文
共 50 条
  • [21] Polymerization of acrylonitrile with (diisopropylamido) bis (indenyl) lanthanides
    Li, G
    Zhang, XQ
    Ying, LQ
    Ba, XW
    Cui, DM
    Tang, T
    Zhang, XQ
    Jin, YT
    JOURNAL OF RARE EARTHS, 2002, 20 (05) : 538 - 540
  • [22] Radiation polymerization of acrylonitrile in a viscous system with styrene
    Badawy, SM
    Dessouki, AM
    JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 84 (02) : 268 - 275
  • [23] Polymerization of Acrylonitrile with(Diisopropylamido) Bis(indenyl) Lanthanides
    李刚
    张学全
    应来强
    巴小微
    崔冬梅
    唐涛
    金鹰泰
    Journal of Rare Earths, 2002, (05) : 538 - 540
  • [24] Preparation and Characterization of Single-Component Poly-α-olefin Oil Base Stocks
    Dong, Su Q.
    Mi, Pu K.
    Xu, Sheng
    Zhang, Jun
    Zhao, Rui D.
    ENERGY & FUELS, 2019, 33 (10) : 9796 - 9804
  • [25] Inkjet-Compatible Single-Component Polydiacetylene Precursors for Thermochromic Paper Sensors
    Yoon, Bora
    Shin, Hyora
    Kang, Eun-Mi
    Cho, Dae Won
    Shin, Kayeong
    Chung, Hoeil
    Lee, Chan Woo
    Kim, Jong-Man
    ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (11) : 4527 - 4535
  • [26] Polymerization of acrylonitrile initiated by samarium diiodide in the presence of hexamethylphosphoramide
    Zhang, TX
    Jiang, LM
    Sun, WL
    Shen, ZQ
    Ma, SM
    EUROPEAN POLYMER JOURNAL, 2002, 38 (11) : 2329 - 2332
  • [27] Group transfer polymerization of acrylonitrile in bulk at ambient temperature
    Junsong Zhang
    Mincan Wang
    Jianhai Wang
    Yanyan Shi
    Jingchao Tao
    Dekun Wang
    Polymer Bulletin, 2005, 54 : 157 - 161
  • [28] Robust Chromium Precursors for Catalysis: Isolation and Structure of a Single-Component Ethylene Tetramerization Precatalyst
    Hirscher, Nathanael A.
    Sierra, Danny Perez
    Agapie, Theodor
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (14) : 6022 - 6029
  • [29] Screening of Catalysts for Acrylonitrile Decomposition
    Tetsuya Nanba
    Shoichi Masukawa
    Junko Uchisawa
    Akira Obuchi
    Catalysis Letters, 2004, 93 : 195 - 201
  • [30] Screening of catalysts for acrylonitrile decomposition
    Nanba, T
    Masukawa, S
    Uchisawa, J
    Obuchi, A
    CATALYSIS LETTERS, 2004, 93 (3-4) : 195 - 201
12345