Metal-free C-H thioarylation of arenes using sulfoxides: a direct, general diaryl sulfide synthesis

被引：87
作者：
Fernandez-Salas, Jose A. [1 ]
Pulis, Alexander P. [1 ]
Procter, David J. [1 ]
机构：
[1] Univ Manchester, Sch Chem, Oxford Rd, Manchester M13 9PL, Lancs, England
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 83期
基金：
英国工程与自然科学研究理事会;
关键词：
CROSS-COUPLING REACTION; SULFUR BOND FORMATION; CATALYZED REGIOSELECTIVE SULFENYLATION; CLAISEN REARRANGEMENT SEQUENCE; NUCLEOPHILIC ORTHO-ALLYLATION; ARYL SULFIDES; ORTHO-PROPARGYLATION; CARBONYL-COMPOUNDS; ROOM-TEMPERATURE; RICH ARENES;
D O I：
10.1039/c6cc07627k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-free C-H thioarylation of arenes and heteroarenes using methyl sulfoxides constitutes a general protocol for the synthesis of high value diaryl sulfides. The coupling of arenes and heteroarenes with in situ activated sulfoxides is regioselective, uses readily available starting materials, is operationally simple, and tolerates a wide range of functional groups.
引用
收藏
页码：12364 / 12367
页数：4
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