A MICROPOROUS METAL-ORGANIC FRAMEWORK WITH OPEN METAL SITES FOR SELECTIVE SENSING Fe3+, CrO42- AND NITROBENZENE

被引:5
|
作者
Wang, Fu-Min [1 ]
Wang, Rui [2 ,3 ]
Han, Yao-Yao [2 ,3 ]
Li, Sa-Ying [1 ]
Man, Jian-Hui [2 ,3 ]
He, Yong-Xiang [2 ,3 ]
Li, Bao-Hong [2 ,3 ]
机构
[1] Shaanxi Xueqian Normal Univ, Dept Chem & Chem Engn, Xian, Shaanxi, Peoples R China
[2] Guangdong Med Univ, Key Lab Res & Dev New Med Mat, Dongguan 523808, Peoples R China
[3] Guangdong Med Univ, Sch Pharm, Dongguan 523808, Peoples R China
关键词
Metal-organic framework; Luminescence quenching; Iron(III); Chromate; Nitrobenzene; LUMINESCENT; RECOGNITION; ZN(II); CU(II); IONS; MOF; COMPLEXES; EMISSION; NI(II); SENSOR;
D O I
10.4314/bcse.v31i2.10
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A 3D network with the (4(2).6.8(3)) topology of metal- organic framework possessing an open 1D channel was synthesized by rigid and planar tetracarboxylic acid 5,5'-(1H-2,3,5-triazole-1,4-diyl) diisophthalic acid (H4L). The luminescent properties of 1 shows highly sensitive response to nitrobenzene, Fe3+ and CrO42- through luminescence quenching effects, making it a promising luminescent sensor for nitro aromatic compounds, Fe3+ and CrO42-.
引用
收藏
页码:291 / 297
页数:7
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