A novel disubstituted Lindqvist-type polyoxomolybdate [Te2Mo4O19]6- supporting two organic vanadyl moieties:: Synthesis, characterization, and crystal structure of {[V(2,2-bipy)2]2(4,4-bipy)[Te2Mo4O19]}

被引：5

作者：

Wang, Jingping ^{[1
]}

Zhang, Guoqian ^{[1
]}

Ma, Pengtao ^{[1
]}

Niu, Jingyang ^{[1
]}

机构：

[1] Henan Univ, Sch Chem & Chem Engn, Inst Mol & Crystal Engn, Kaifeng 475001, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 07期

基金：

中国国家自然科学基金;

关键词：

hydrothermal synthesis; Lindqvist anion; polyoxomolybdate; crystal structure;

D O I：

10.1016/j.inoche.2008.03.037

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first example of disubstituted Lindqvist-type polyoxomolybdate {[V(2,2-bipy)(2)](2)(4,4-bipy)[Te2Mo4O19]} has been synthesized hydrothermally and characterized by elemental analyses, XPS, IR, TG-DTA and X-ray single crystal diffraction. The structural analysis shows that the neutral molecular unit [V(2,2-bipy)(2)](2)[Te2Mo4O19] consists of a novel Lindqvist-type polyanion [Te2Mo4O19](6-) supporting two vanadyl moieties [V(2,2-bipy)(2)](3+), and such neutral molecules are joined together by pi-pi stacking interactions between the pyridine groups to form a two-dimensional grid-like network with non-coordinating "guest" 4,4-bipys encapsulated. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：825 / 828

页数：4

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