Calixpyrroles II

被引:454
|
作者
Gale, PA [1 ]
Anzenbacher, P
Sessler, JL
机构
[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England
[2] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA
[3] Univ Texas, Inst Cellular & Mol Biol, Austin, TX 78712 USA
[4] Bowling Green State Univ, Dept Chem, Bowling Green, OH 43403 USA
[5] Bowling Green State Univ, Ctr Photochem Sci, Bowling Green, OH 43403 USA
基金
英国工程与自然科学研究理事会; 美国国家科学基金会; 美国国家卫生研究院;
关键词
calixpyrrole; anion binding; porphyrinogen; sensors; macrocycles;
D O I
10.1016/S0010-8545(01)00346-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This review article is the second in a series covering advances in the synthetic and molecular recognition chemistry of calixpyrrole macrocycles (meso-octasubstituted porphyrinogens). Significant progress has been made in the last three years in the use of calix[4]pyrroles as redox-active or optical sensors for anions. This period has also been marked by a number of preparative advances, including the synthesis of N-confused calix[4]pyrroles, the synthesis of extended cavity calix[4]pyrroles, and the synthesis of 'higher order' or 'expanded' calix[n]pyrroles (n > 4). (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:57 / 102
页数:46
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