X-ray Spectroscopies Revealing the Structure and Dynamics of Metalloprotein Active Centers

被引：21

作者：

Aziz, Emad F. ^{[1
,2
]}

机构：

[1] Helmholtz Zentrum Berlin Mat & Energie, D-12489 Berlin, Germany

[2] Free Univ Berlin, FB Phys, D-14195 Berlin, Germany

来源：

JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2011年 / 2卷 / 04期

关键词：

NMR STRUCTURE DETERMINATION; ABSORPTION FINE-STRUCTURE; L-EDGE; ELECTRONIC-STRUCTURE; CHARGE-TRANSFER; NOESY SPECTRA; AMINO-ACID; MYOGLOBIN; HEMOGLOBIN; PROTEIN;

D O I：

10.1021/jz1014778

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reactions catalyzed by metalloproteins occur at the active centers, making them the focus of many spectroscopic investigations in an attempt to determine their structure. Here, an overview of the recent achievements and the current developments of X-ray spectroscopies using synchrotron light sources is presented. Their potential for investigating protein structure and dynamics is discussed.

引用

页码：320 / 326

页数：7

共 59 条

[1] Tetrathiomolybdate Inhibits Copper Trafficking Proteins Through Metal Cluster Formation [J].

Alvarez, Hamsell M. ;

Xue, Yi ;

Robinson, Chandler D. ;

Canalizo-Hernandez, Monica A. ;

Marvin, Rebecca G. ;

Kelly, Rebekah A. ;

Mondragon, Alfonso ;

Penner-Hahn, James E. ;

O'Halloran, Thomas V. .

SCIENCE, 2010, 327 (5963) :331-334

[2] Experimental aspects of biological X-ray absorption spectroscopy [J].

Ascone, I ;

Meyer-Klaucke, W ;

Murphy, L .

JOURNAL OF SYNCHROTRON RADIATION, 2003, 10 :16-22

[3] Steric hindrance of ion-ion interaction in electrolytes [J].

Aziz, EF ;

Freiwald, M ;

Eisebitt, S ;

Eberhardt, W .

PHYSICAL REVIEW B, 2006, 73 (07)

[4] Molecular and electronic structure in NaCl electrolytes of varying concentration: Identification of spectral fingerprints [J].

Aziz, EF ;

Zimina, A ;

Freiwald, M ;

Eisebitt, S ;

Eberhardt, W .

JOURNAL OF CHEMICAL PHYSICS, 2006, 124 (11)

[5] Localized charge transfer in a molecularly doped conducting polymer [J].

Aziz, Emad E. ;

Vollmer, Antje ;

Eisebitt, Stefan ;

Eberhardt, Wolfgang ;

Pingel, Patrick ;

Neher, Dieter ;

Koch, Norbert .

ADVANCED MATERIALS, 2007, 19 (20) :3257-+

[6] Cation-specific interactions with carboxylate in amino acid and acetate aqueous solutions:: X-ray absorption and ab initio calculations [J].

Aziz, Emad F. ;

Ottosson, Niklas ;

Eisebitt, Stefan ;

Eberhardt, Wolfgang ;

Jagoda-Cwiklik, Barbara ;

Vacha, Robert ;

Jungwirth, Pavel ;

Winter, Bernd .

JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (40) :12567-12570

[7] Effect of cysteine vs. histidine on the electronic structure of Zn2+ upon complex formation [J].

Aziz, Emad F. ;

Eberhardt, W. ;

Eisebitt, S. .

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2008, 222 (5-6) :727-738

[8] Interaction between liquid water and hydroxide revealed by core-hole de-excitation [J].

Aziz, Emad F. ;

Ottosson, Niklas ;

Faubel, Manfred ;

Hertel, Ingolf V. ;

Winter, Bernd .

NATURE, 2008, 455 (7209) :89-91

[9] Existence of oriented ion-hydroxide clusters in concentrated aqueous NaCl solution at pH 13 [J].

Aziz, Emad F. ;

Eisebitt, Stefan ;

Eberhardt, Wolfgang ;

Cwiklik, Lukasz ;

Jungwirth, Pavel .

JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (04) :1262-1266

[10] Photoinduced formation of N2 molecules in ammonium compounds [J].

Aziz, Emad F. ;

Grasjo, Johan ;

Forsberg, Johan ;

Andersson, Egil ;

Soderstrom, Johan ;

Duda, Laurent ;

Zhang, Wenhua ;

Yang, Jinglong ;

Eisebitt, Stefan ;

Bergstrom, Christel ;

Luo, Yi ;

Nordgren, Joseph ;

Eberhardt, Wolfgang ;

Rubensson, Jan-Erik .

JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 111 (39) :9662-9669

← 1 2 3 4 5 6 →