Low-temperature synthesis of the infinite-layer compound LaNiO2 using CaH2 as reductant

被引：9

作者：

Takamatsu, Tomohisa ^{[1
]}

Kato, Masatsune ^{[1
]}

Noji, Takashi ^{[1
]}

Koike, Yoji ^{[1
]}

机构：

[1] Tohoku Univ, Dept Appl Phys, Aoba Ku, Sendai, Miyagi 9808579, Japan

来源：

PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS | 2010年 / 470卷

关键词：

LaNiO2; Infinite-layer; CaH2; Low-temperature synthesis; OXIDE;

D O I：

10.1016/j.physc.2009.10.132

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

We have successfully synthesized bulk samples of the infinite-layer compound LaNiO2 by reduction of the perovskite LaNiO3 using CaH2. First, LaNiO3 has been prepared using molten KOH at 450 degrees C. Next, the infinite-layer compound LaNiO2 has been synthesized by heating LaNiO3 mixed with a double stoichiometric excess of CaH2 in an evacuated Pyrex tube at 300 degrees C for 24 h. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：S764 / S765

页数：2

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