Solvent-induced intercluster rearrangements and the reversible luminescence responses in sulfide bridged gold(I)-silver(I) clusters

被引：64
作者：
Mo, Li-Qin [1 ]
Jia, Jian-Hua [1 ]
Sun, Li-jia [1 ]
Wang, Quan-Ming [1 ]
机构：
[1] Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Coll Chem & Chem Engn, Xiamen 361005, Fujian, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 69期
关键词：
VOLATILE ORGANIC-COMPOUNDS; VAPOCHROMIC BEHAVIOR; COMPLEXES;
D O I：
10.1039/c2cc33446a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Blue or yellow-green emission is observed from two different crystal types of the same gold(I)-silver(I) molecular cluster [SAu3Ag(L1)(3)](BF4)(2) (L1 = 2-diphenylphosphino-4-methylpyridine) depending on the crystallization conditions; structural data suggest that intermolecular Au center dot center dot center dot Au interactions account for the luminescence vapochromic responses; a similar observation was made on two other pairs of analogues.
引用
收藏
页码：8691 / 8693
页数：3
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