Functionalised [(NHC)Pd(allyl)Cl] complexes: Synthesis, immobilisation and application in cross-coupling and dehalogenation reactions

被引：23

作者：

Collinson, John-Michael ^{[1
]}

Wilton-Ely, James D. E. T. ^{[1
]}

Diez-Gonzalez, Silvia ^{[1
]}

机构：

[1] Imperial Coll London, Dept Chem, South Kensington Campus, London SW7 2AZ, England

来源：

CATALYSIS COMMUNICATIONS | 2016年 / 87卷

基金：

英国工程与自然科学研究理事会;

关键词：

Cross-coupling; Dehalogenation; N-Heterocyclic carbene; Palladium complexes; Transfer hydrogenation; N-HETEROCYCLIC CARBENES; CLICK CHEMISTRY; SUZUKI-MIYAURA; CATALYSTS; HYDROGENATION; NHC; NANOPARTICLES; PERSPECTIVE;

D O I：

10.1016/j.catcom.2016.09.006

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel NHC-palladium(II) (NHC = N-heterocyclic carbene) complex and its immobilised version have been prepared and fully characterised. Optimisation studies led to good catalytic activities in Suzuki-Miyaura cross coupling and chloroarene dehalogenation reactions. Furthermore, the unexpected palladium-mediated transfer hydrogenation of a carbonyl compound is reported. (C) 2016 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license.

引用

页码：78 / 81

页数：4

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