Polysilalkylene or silarylene siloxanes said hybrid silicones

被引：21

作者：

Guida-Pietrasanta, F ^{[1
]}

Boutevin, B ^{[1
]}

机构：

[1] Ecole Natl Super Chim Montpellier, CNRS, UMR 5076, Lab Chim Macromol, F-34296 Montpellier, France

来源：

INORGANIC POLYMERIC NANOCOMPOSITES AND MEMBRANES | 2005年 / 179卷

关键词：

fluorinated polysiloxanes; hydrosilylation; polycarbosiloxanes; polycondensation; polysilalkylene siloxanes; polysilarylene siloxanes;

D O I：

10.1007/b104479

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This paper reviews different methods of synthesis of polysilalkylene or silarylene siloxanes that are sometimes called "hybrid" silicones. This special type of silicone has been developed to avoid the drawback of the depolymerization of classical polysiloxanes in certain conditions and to obtain elastomers with enhanced thermal and fuel resistance properties. These silicones have been prepared through two main routes: the polycondensation of alpha, omega-bis silanol monomers (prepared either via an organometallic route or via hydrosilylation of alpha, omega-dienes) and the polyhydrosilylation of alpha, omega-dienes with dihydrodisiloxanes or oligosiloxanes.

引用

页码：1 / 27

页数：27

共 88 条

[51] Carbon-Silicon coupling between fluorenyl Grignard reagents and dichlorosilanes for synthesis of novel copolymers and chemical properties of the copolymers [J].