Polysilalkylene or silarylene siloxanes said hybrid silicones

被引：21
作者：
Guida-Pietrasanta, F [1 ]
Boutevin, B [1 ]
机构：
[1] Ecole Natl Super Chim Montpellier, CNRS, UMR 5076, Lab Chim Macromol, F-34296 Montpellier, France
来源：
INORGANIC POLYMERIC NANOCOMPOSITES AND MEMBRANES | 2005年 / 179卷
关键词：
fluorinated polysiloxanes; hydrosilylation; polycarbosiloxanes; polycondensation; polysilalkylene siloxanes; polysilarylene siloxanes;
D O I：
10.1007/b104479
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
This paper reviews different methods of synthesis of polysilalkylene or silarylene siloxanes that are sometimes called "hybrid" silicones. This special type of silicone has been developed to avoid the drawback of the depolymerization of classical polysiloxanes in certain conditions and to obtain elastomers with enhanced thermal and fuel resistance properties. These silicones have been prepared through two main routes: the polycondensation of alpha, omega-bis silanol monomers (prepared either via an organometallic route or via hydrosilylation of alpha, omega-dienes) and the polyhydrosilylation of alpha, omega-dienes with dihydrodisiloxanes or oligosiloxanes.
引用
收藏
页码：1 / 27
页数：27
相关论文
共 88 条
  • [1] Synthesis of hybrid fluorinated silicones .1. Influence of the spacer between the silicon atom and the fluorinated chain in the preparation and the thermal properties of hybrid homopolymers
    Ameduri, B
    Boutevin, B
    GuidaPietrasanta, F
    Manseri, A
    Ratsimihety, A
    Caporiccio, G
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1996, 34 (15) : 3077 - 3090
  • [2] New fluorinated thermoplastic elastomers.: I.: The synthesis and thermal characteristics of α,ω-dihydrosilane hybrid fluorinated polysiloxane precursors
    Andre, S
    Guida-Pietrasanta, F
    Rousseau, A
    Boutevin, B
    Caporiccio, G
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (24) : 4485 - 4492
  • [3] Andre S, 2000, MACROMOL CHEM PHYSIC, V201, P2309, DOI 10.1002/1521-3935(20001101)201:17<2309::AID-MACP2309>3.0.CO
  • [4] 2-P
  • [5] Novel synthesis of polyimide-polyhybridsiloxane block copolymers via polyhydrosilylation: Characterization and physical properties
    Andre, S
    Guida-Pietrasanta, F
    Rousseau, A
    Boutevin, B
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2001, 39 (14) : 2414 - 2425
  • [6] ANDRIANOV KA, 1971, VYSOKOMOL SOEDIN A, V13, P937
  • [7] ANDRIANOV KA, 1968, ZH OBSHCH KHIM, V38, P175
  • [8] Hybrid silalkylene polysiloxanes: Synthesis and thermal properties
    Benouargha, A
    Boutevin, B
    Caporiccio, G
    Essassi, E
    GuidaPietrasanta, F
    Ratsimihety, A
    [J]. EUROPEAN POLYMER JOURNAL, 1997, 33 (07) : 1117 - 1124
  • [9] SYNTHESIS OF FLUORINATED POLYSILOXANES .6. OLIGOMERS OF POLYDIMETHYLSILOXANES WITH FLUORINATED END-GROUPS OBTAINED BY CONDENSATION OF FLUORINATED CHLOROSILANES WITH ALPHA,OMEGA-DISILANOLS
    BOUTEVIN, B
    PIETRASANTA, Y
    YOUSSEF, B
    [J]. JOURNAL OF FLUORINE CHEMISTRY, 1988, 39 (01) : 61 - 73
  • [10] Poly-silafluoroalkyleneoligosiloxanes: a class of fluoroelastomers with low glass transition temperature
    Boutevin, B
    Caporiccio, G
    Guida-Pietrasanta, F
    Ratsimihety, A
    [J]. JOURNAL OF FLUORINE CHEMISTRY, 2003, 124 (02) : 131 - 138
123456789