Unsymmetrical Tripodal Phosphine Oxide with Triazole Groups: Synthesis and Molecular Structure

被引：3

作者：

Bykhovskaya, O., V ^{[1
]}

Kudryavtsev, I. Yu ^{[1
]}

Baulina, T., V ^{[1
]}

Pasechnik, M. P. ^{[1
]}

Vologzhanina, A. V. ^{[1
]}

Matveeva, A. G. ^{[1
]}

Moiseeva, A. A. ^{[1
]}

Brel, V. K. ^{[1
]}

机构：

[1] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2022年 / 92卷 / 08期

基金：

俄罗斯科学基金会;

关键词：

tripodal ligands with 1; 2; 3-triazole groups; functionalized triarylphosphine oxides; Mitsunobu reaction; CO(II) COMPLEXES; SPIN-CROSSOVER; ACID; TRIPHENYLPHOSPHINE; COORDINATION; RECOGNITION; RECEPTORS; LIGANDS; EXTRACTION; FE(II);

D O I：

10.1134/S1070363222080084

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Mitsunobu reaction of tris(2-hydroxyphenyl)phosphine oxide with 3-butyn-1-ol has afforded bis[2-(3 ''-butynyloxy)phenyl](2 '-hydroxyphenyl)phosphine oxide, which has been converted into the corresponding triazole via click reaction with PhN3. Asymmetric tripodal ligand containing three 1,2,3-triazole groups in the molecule has been prepared from this triazole via the reaction with propargyl bromide and PhN3. Structure of the ligand has been elucidated by means of single-crystal X-ray diffraction analysis.

引用

页码：1420 / 1429

页数：10

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