Efficient organo-photocatalysis system of an n-type perylene derivative/p-type cobalt phthalocyanine bilayer for the production of molecular hydrogen from hydrazine

被引：20

作者：

Abe, Toshiyuki ^{[1
]}

Tanno, Yoshinori ^{[1
]}

Taira, Naohiro ^{[1
]}

Nagai, Keiji ^{[2
]}

机构：

[1] Hirosaki Univ, Grad Sch Sci & Technol, Dept Frontier Mat Chem, Hirosaki, Aomori 0368561, Japan

[2] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

RSC ADVANCES | 2015年 / 5卷 / 57期

关键词：

VISIBLE-LIGHT; WATER PHASE; FULL-SPECTRUM; SOLAR-CELLS; THIN-FILMS; EVOLUTION; WORKING; DECOMPOSITION; CATALYSTS; NITROGEN;

D O I：

10.1039/c5ra03842a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The stoichiometric decomposition of hydrazine (N2H4) into N-2 and H-2 was observed to occur efficiently in a photocatalysis system of an organic p-n bilayer. The primary feature of the present system is that the entire visible-light energy spectrum can be utilised for N2H4 decomposition. Furthermore, this paper presents the first demonstration of H-2 formation by the reducing power photogenerated at the n-type perylene derivative in an organic bilayer.

引用

页码：46325 / 46329

页数：5

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