Syntheses and metal-ion binding properties of calix[4]arene derivatives containing soft donor atoms:: Highly selective extraction reagents for Ag+

被引：22

作者：

Xie, J ^{[1
]}

Zheng, QY ^{[1
]}

Zheng, YS ^{[1
]}

Chen, CF ^{[1
]}

Huang, ZT ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, LMRSS, Beijing 100080, Peoples R China

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2001年 / 40卷 / 1-2期

关键词：

calix[4]arenes; calix[4](thia)crowns; metal-ion extraction;

D O I：

10.1023/A:1011196722928

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of calix[4]arene derivatives containing N or S atoms at the lower rim were synthesized by etherification of OH groups and their metal-ion extraction abilities were studied. The extraction selectivity for Ag+ over other ions with these novel receptors was outstanding. Among these ligands, calix[4]arene podand, which possessed two linear ligands, has shown better binding ability with Ag+ than calix[4]crowns.

引用

页码：125 / 130

页数：6

共 29 条

[11]

Gutsche C. D., 1998, CALIXARENE REVISITED

[12]

Gutsche C.D., 1989, ORG SYNTH, V68, P234

[13]

Gutsche C.D., 1989, CALIXARENE

[14]

HARRIS SJ, 1990, Patent No. 0432989

[15] Novel cavity design using calix[n]arene skeletons: Toward molecular recognition and metal binding [J].

Ikeda, A ;

Shinkai, S .

CHEMICAL REVIEWS, 1997, 97 (05) :1713-1734

[16] MOLECULAR DESIGN OF CROWN ETHERS .3. EXTRACTION OF ALKALINE-EARTH AND HEAVY-METAL PICRATES WITH 14-CROWN-5 TO 17-CROWN-5 AND 17-CROWN-6 TO 22-CROWN-6 [J].

INOUE, Y ;

OUCHI, M ;

HAKUSHI, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (02) :525-530

[17]

König B, 1999, EUR J INORG CHEM, P1557

[18] Calixarenes in analytical and separation chemistry [J].

Ludwig, R .

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 2000, 367 (02) :103-128

[19] SOLVENT-EXTRACTION OF SILVER AND THALLIUM PICRATES WITH POLY-(CROWN ETHER)S AND BIS-(CROWN ETHER)S [J].

MAEDA, T ;

KIMURA, K ;

SHONO, T .

FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1979, 298 (05) :363-366

[20]

McKervey M.A., 1996, COMPREHENSIVE SUPRAM, V1

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