Syntheses and metal-ion binding properties of calix[4]arene derivatives containing soft donor atoms:: Highly selective extraction reagents for Ag+

被引：22

作者：

Xie, J ^{[1
]}

Zheng, QY ^{[1
]}

Zheng, YS ^{[1
]}

Chen, CF ^{[1
]}

Huang, ZT ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, LMRSS, Beijing 100080, Peoples R China

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2001年 / 40卷 / 1-2期

关键词：

calix[4]arenes; calix[4](thia)crowns; metal-ion extraction;

D O I：

10.1023/A:1011196722928

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of calix[4]arene derivatives containing N or S atoms at the lower rim were synthesized by etherification of OH groups and their metal-ion extraction abilities were studied. The extraction selectivity for Ag+ over other ions with these novel receptors was outstanding. Among these ligands, calix[4]arene podand, which possessed two linear ligands, has shown better binding ability with Ag+ than calix[4]crowns.

引用

页码：125 / 130

页数：6

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