Selective etching of spin-coated and thermally evaporated As30S45Se25 thin films

被引:17
作者
Palka, K. [1 ,2 ]
Slang, S. [2 ]
Buzek, J. [1 ]
Vlcek, M. [2 ]
机构
[1] Univ Pardubice, Fac Chem Technol, Dept Gen & Inorgan Chem, Pardubice 53210, Czech Republic
[2] Univ Pardubice, Fac Chem Technol, Ctr Mat & Nanotechnol, Pardubice 53210, Czech Republic
关键词
Chalcogenide glasses; Selective etching; Thin films; AS-S-SE; OPTICAL-PROPERTIES; CHALCOGENIDE GLASS; RAMAN-SCATTERING; SYSTEM; DISSOLUTION; SELENIUM; SPECTRA; AMINES; LAYERS;
D O I
10.1016/j.jnoncrysol.2016.05.042
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Chalcogenide glasses are intensively studied materials due to their interesting optical properties such as high values of refractive index, wide transparency in IR, photosensitivity, etc. We report on the comparison of photo and thermo-induced changes in optical properties and chemical resistance of thermally evaporated and spin coated As30S45Se25 thin films. Significantly different trends of photo-induced changes in chemical resistance in both types of thin films such as negative etching of thermally evaporated thin films and positive etching of spin-coated thin films were observed. The structural changes responsible for the observed phenomena were investigated as well. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:104 / 109
页数:6
相关论文
共 35 条
[11]  
HOLOMB R, 2011, PHYS STATUS SOLIDI C, V8, P2705, DOI DOI 10.1002/PSSC.201084058
[12]   Structural and optical changes in AS2S3 thin films induced by light ion irradiation [J].
Ivan, I ;
Veres, M ;
Pócsik, I ;
Kokenyesi, S .
PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 2004, 201 (14) :3193-3199
[13]   Optical properties and scanning probe microscopy study of some Ag - As - S - Se amorphous films [J].
Knotek, P. ;
Tasseva, J. ;
Petkov, K. ;
Kincl, M. ;
Tichy, L. .
THIN SOLID FILMS, 2009, 517 (20) :5943-5947
[14]   Surface morphology of spin-coated As-S-Se chalcogenide thin films [J].
Kohoutek, T. ;
Wagner, T. ;
Orava, J. ;
Krbal, M. ;
Fejfar, A. ;
Mates, T. ;
Kasap, S. O. ;
Frumar, M. .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2007, 353 (13-15) :1437-1440
[15]   The comparison of Ag-As33S67 films prepared by thermal evaporation (TE), spin-coating (SC) and a pulsed laser deposition (PLD) [J].
Krbal, M. ;
Wagner, T. ;
Kohoutek, T. ;
Nemec, P. ;
Orava, J. ;
Frumar, M. .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2007, 68 (5-6) :953-957
[16]  
Li W, 2005, J APPL PHYS, V98, DOI [10.1063/1.2099514, 10.1063/1.2009815]
[17]   Mechanism of photostructural changes in mixed-chalcogen As-S-Se glasses investigated by Raman spectroscopy [J].
Lin, Fang-Yin ;
Gulbiten, Ozgur ;
Yang, Zhiyong ;
Calvez, Laurent ;
Lucas, Pierre .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2011, 44 (04)
[18]   Selective wet etching of amorphous As2Se3 thin films [J].
Loghina, L. ;
Palka, K. ;
Buzek, J. ;
Slang, S. ;
Vlcek, M. .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2015, 430 :21-24
[19]   Comparison of the optical, thermal and structural properties of Ge-Sb-S thin films deposited using thermal evaporation and pulsed laser deposition techniques [J].
Musgraves, J. D. ;
Carlie, N. ;
Hu, J. ;
Petit, L. ;
Agarwal, A. ;
Kimerling, L. C. ;
Richardson, K. A. .
ACTA MATERIALIA, 2011, 59 (12) :5032-5039
[20]   Selective wet-etching and characterization of chalcogenide thin films in inorganic alkaline solutions [J].
Orava, J. ;
Wagner, T. ;
Krbal, A. ;
Kohoutek, T. ;
Vlcek, Mil. ;
Frumar, M. .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2007, 353 (13-15) :1441-1445