Synthesis and Oxygen Storage Capacity of Two-Dimensional Ceria Nanocrystals

被引:171
作者
Wang, Dianyuan [1 ,3 ]
Kang, Yijin [1 ]
Doan-Nguyen, Vicky [2 ]
Chen, Jun [2 ]
Kuengas, Rainer [4 ]
Wieder, Noah L. [4 ]
Bakhmutsky, Kevin [4 ]
Gorte, Raymond J. [4 ]
Murray, Christopher B. [1 ,2 ]
机构
[1] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA
[2] Univ Penn, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
[3] Jiujiang Univ, Coll Sci, Jiujiang 332005, Peoples R China
[4] Univ Penn, Dept Chem & Biomol Engn, Philadelphia, PA 19104 USA
基金
美国国家科学基金会; 中国国家自然科学基金;
关键词
ceria; morphology control; nanoplates; nanostructures; oxygen storage; SHAPE-CONTROLLED SYNTHESIS; GAS-SHIFT REACTION; SELECTIVE SYNTHESIS; AU-CEO2; CATALYSTS; NANOPARTICLES; SIZE; NANOSTRUCTURES; NANOPOLYHEDRA; REDUCTION; OXIDATION;
D O I
10.1002/anie.201101043
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Small plate structure makes big difference: A facile synthetic method for high-quality ceria nanoplates enclosed by (100) facets involves the usage of a mineralizer. Compared to the 3D ceria nanomaterials prepared by combustion and hydrothermal treatment, the ceria nanoplates exhibit superior oxygen storage properties (see picture). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:4378 / 4381
页数:4
相关论文
共 52 条
[1]  
[Anonymous], 2005, ANGEW CHEM-GER EDIT, DOI DOI 10.1002/ANGE.200462573
[2]  
[Anonymous], ANGEW CHEM
[3]   Studies of the water-gas-shift reaction on ceria-supported Pt, Pd, and Rh: implications for oxygen-storage properties [J].
Bunluesin, T ;
Gorte, RJ ;
Graham, GW .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1998, 15 (1-2) :107-114
[4]   Synthesis of square gadolinium-oxide nanoplates [J].
Cao, YC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (24) :7456-7457
[5]   Synthesis of Dispersible Pd@CeO2 Core-Shell Nanostructures by Self-Assembly [J].
Cargnello, Matteo ;
Wieder, Noah L. ;
Montini, Tiziano ;
Gorte, Raymond J. ;
Fornasiero, Paolo .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (04) :1402-1409
[6]   Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts [J].
Choi, Minkee ;
Na, Kyungsu ;
Kim, Jeongnam ;
Sakamoto, Yasuhiro ;
Terasaki, Osamu ;
Ryoo, Ryong .
NATURE, 2009, 461 (7261) :246-U120
[7]   High-Flux Solar-Driven Thermochemical Dissociation of CO2 and H2O Using Nonstoichiometric Ceria [J].
Chueh, William C. ;
Falter, Christoph ;
Abbott, Mandy ;
Scipio, Danien ;
Furler, Philipp ;
Haile, Sossina M. ;
Steinfeld, Aldo .
SCIENCE, 2010, 330 (6012) :1797-1801
[8]   COMPUTER MODELING OF SURFACES AND DEFECTS ON CERIUM DIOXIDE [J].
CONESA, JC .
SURFACE SCIENCE, 1995, 339 (03) :337-352
[9]   Binary nanocrystal superlattice membranes self-assembled at the liquid-air interface [J].
Dong, Angang ;
Chen, Jun ;
Vora, Patrick M. ;
Kikkawa, James M. ;
Murray, Christopher B. .
NATURE, 2010, 466 (7305) :474-477
[10]   Nanostructured Au-CeO2 catalysts for low-temperature water-gas shift [J].
Fu, Q ;
Weber, A ;
Flytzani-Stephanopoulos, M .
CATALYSIS LETTERS, 2001, 77 (1-3) :87-95