Removal of zinc and lead ions by polymer-enhanced ultrafiltration using unmodified starch as novel binding polymer

被引:19
作者
Baharuddin, N. H. [1 ]
Sulaiman, N. M. N. [1 ]
Aroua, M. K. [1 ]
机构
[1] Univ Malaya, Dept Chem Engn, Kuala Lumpur 50603, Malaysia
关键词
Complexing agents; Metals; Polyethyleneimine; Separation; Water soluble; HEAVY-METAL IONS; POLYETHYLENEIMINE PEI; COMPLEXATION; WATER;
D O I
10.1007/s13762-014-0549-4
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The removal of zinc and lead from aqueous dilute solutions by polymer-enhanced ultrafiltration process using unmodified starch as a new binding polymer was studied. Experiments were performed to determine the effects of transmembrane pressure, pH, concentration of metal ions on the retention and permeate flux. The performance of the proposed new binding polymer was compared to that of polyethyleneimine a conventional polymer frequently used in polymer-enhanced ultrafiltration. The retention of zinc and lead ions reached 96 and 66 %, respectively, using 0.05 % unmodified starch at pH 7. Overall unmodified starch showed better retention for zinc ions then polyethyleneimine, whereas polyethyleneimine retention for lead ions was higher. Solution pH was found to have little effect on flux.
引用
收藏
页码:1825 / 1834
页数:10
相关论文
共 34 条
[1]   Ultrafiltration of water containing natural organic matter: heavy metal removing in the hybrid complexation-ultrafiltration process [J].
Alpatova, A ;
Verbych, S ;
Bryk, M ;
Nigmatullin, R ;
Hilal, N .
SEPARATION AND PURIFICATION TECHNOLOGY, 2004, 40 (02) :155-162
[2]  
Alto K., 1977, Toxicity of xanthates to freshwater fish and invertebrates
[3]  
Aratani T., 1983, Removal of metals in combined treatment systems
[4]   Removal of chromium ions from aqueous solutions by polymer-enhanced ultrafiltration [J].
Aroua, Mohamed Kheireddine ;
Zuki, Fathiah Mohamed ;
Sulaiman, Nik Meriam .
JOURNAL OF HAZARDOUS MATERIALS, 2007, 147 (03) :752-758
[5]   Polymer-enhanced ultrafiltration process for heavy metals removal from industrial wastewater [J].
Barakat, M. A. ;
Schmidt, E. .
DESALINATION, 2010, 256 (1-3) :90-93
[6]   Starches of Some Food Crops, Changes During Processing and Their Nutraceutical Potential [J].
Bello-Perez, L. A. ;
Paredes-Lopez, O. .
FOOD ENGINEERING REVIEWS, 2009, 1 (01) :50-65
[7]  
Bertolini A., 2009, Starches: Characterization, properties, and applications, P71
[8]   SOLUBLE POLYMERS IN WATER-PURIFICATION [J].
BOLTO, BA .
PROGRESS IN POLYMER SCIENCE, 1995, 20 (06) :987-1041
[9]  
Bosch X., 2003, Science, V609, P1
[10]   Removal of heavy metal ions by polymer enhanced ultrafiltration Batch process modeling and thermodynamics of complexation reactions [J].
Camarillo, Rafael ;
Perez, Angel ;
Canizares, Pablo ;
de Lucas, Antonio .
DESALINATION, 2012, 286 :193-199