Molecular modelling of the stress-strain behaviour of elastomers in pure shear

被引:1
|
作者
Cail, JI [1 ]
Stepto, RFT [1 ]
机构
[1] Univ Manchester, Sch Mat, Polymer Sci & Technol Grp, Manchester M1 7HS, Lancs, England
关键词
polymer networks; pure shear; Monte-Carlo modelling;
D O I
10.1016/j.polymer.2005.02.038
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
It is demonstrated that experimental stress-strain data for several types of polymer network under pure shear display an approximately universal behaviour. The Monte-Carlo network-modelling method of Stepto, Taylor and Cail is extended to treat stress-strain behaviour in pure shear and its predictions are in good agreement with the experimental data. The predictions of Gaussian network theory are shown to be seriously in error. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4355 / 4360
页数:6
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