Copper(II) complex anchored on magnetic chitosan functionalized trichlorotriazine: An efficient heterogeneous catalyst for the synthesis of tetrazole derivatives

被引：19

作者：

Nasrollahzadeh, Mahmoud ^{[1
]}

Motahharifar, Narjes ^{[1
]}

Nezafat, Zahra ^{[1
]}

Shokouhimehr, Mohammadreza ^{[2
]}

机构：

[1] Univ Qom, Dept Chem, Fac Sci, Qom 37185359, Iran

[2] Seoul Natl Univ, Res Inst Adv Mat, Dept Mat Sci & Engn, Seoul 08826, South Korea

来源：

COLLOID AND INTERFACE SCIENCE COMMUNICATIONS | 2021年 / 44卷

关键词：

5-Arylamino-1H-tetrazole; Arylcyanamide; Chitosan; Fe3O4@CS-TCT-Tet-Cu(II); Heterogeneous catalyst; N-Sulfonyl-N-aryl tetrazoles; LIGANDS; SYSTEM; ACID;

D O I：

10.1016/j.colcom.2021.100471

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this work, a method has been developed for the synthesis of magnetic chitosan functionalized trichlorotriazine-5-amino-1H-tetrazole copper(II) complex (Fe3O4@CS-TCT-Tet-Cu(II)). The synthesized Fe3O4@CS-TCT-Tet-Cu(II) was characterized using XRD, EDS, elemental mapping, STEM, FT-IR, TG/DTA, FFT, ICP-MS, and TEM analyses. Fe3O4@CS-TCT-Tet-Cu(II) was then applied in the synthesis of N-sulfonyl-N-aryl tetrazoles and 5-arylamino-1H-tetrazoles via the reaction of sodium azide with N-sulfonyl-N-arylcyanamides and arylcyanamides, respectively in DMF solvent. The synthesized Fe3O4@CS-TCT-Tet-Cu(II) can be recycled and reused for five cycles with no considerable loss of catalytic performance.

引用

页数：13

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