Hydrazine and Urea Fueled-Solution Combustion Method for Bi2O3 Synthesis: Characterization of Physicochemical Properties and Photocatalytic Activity

被引:19
作者
Astuti, Yayuk [1 ]
Elesta, Prisca Putri [1 ]
Widodo, Didik Setyo [1 ]
Widiyandari, Hendri [2 ]
Balgis, Ratna [3 ]
机构
[1] Diponegoro Univ, Fac Sci & Math, Chem Dept, Jl Prof Soedarto,Kampus Undip Tembalang, Semarang 50275, Indonesia
[2] Univ Sebelas Maret, Fac Math & Nat Sci, Dept Phys, Jl Ir Sutami 36A, Jebres 57126, Surakarta, Indonesia
[3] Hiroshima Univ, Fac Engn, Dept Chem Engn, 141 Kagamiyama, Higashihiroshima, Hiroshima 7398527, Japan
关键词
Bismuth Oxide; Solution Combustion; Photocatalysis; Rhodamine B; Fuels; OXIDE NANOPARTICLES; RHODAMINE-B; BISMUTH; DEGRADATION; NANOSPHERES;
D O I
10.9767/bcrec.15.1.5483.104-111
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Bismuth oxide synthesis using solution combustion method fuelled by hydrazine and urea has been conducted. This study aims to examine the effect of the applied fuels, urea and hydrazine, on product characteristics and photocatalytic activity in degrading rhodamine B dye. Bismuth oxide synthesis was initiated by dissolving bismuth nitrate pentahydrate (Bi(NO3)(3)center dot 5H(2)O) in a nitric acid solvent. Fuel was added and then stirred. The solution formed was heated at 300 degrees C for 8 hours. The product obtained was then calcined at 700 degrees C for 4 hours. Bismuth oxide synthesized with urea (BO1) and hydrazine (BO2) as fuels both obtained form of yellow powder. The formation of bismuth oxide is indicated by the vibrations of the Bi-O-Bi and Bi-O groups and the crystal structure of alpha-Bi2O3 in both products. Photocatalytic activity test showed that BO1 has a photocatalyst activity in degrading rhodamine B higher than that of BO2 with constant values of 3.83x10(-5) s(-1) and 3.43x10(-5) s(-1), respectively. The high photocatalytic activity can be examined through several factors, such as: band gap values, crystal structure, morphology, and surface area, acquired as a result of the use of different fuels in the synthesis process. Copyright (C) 2020 BCREC Group. All rights reserved
引用
收藏
页码:104 / 111
页数:8
相关论文
共 39 条
  • [1] Aruna S.T., 2018, CURRENT OPINION SOLI, V12, P44
  • [2] Synthesis of α-Bismuth oxide using solution combustion method and its photocatalytic properties
    Astuti, Y.
    Fauziyah, A.
    Nurhayati, S.
    Wulansari, A. D.
    Andianingrum, R.
    Hakim, A. R.
    Bhaduri, G.
    [J]. 10TH JOINT CONFERENCE ON CHEMISTRY, 2016, 107
  • [3] Astuti Y, 2017, BULL CHEM REACT ENG, V12, P478, DOI 10.9767/bcrec.12.3.1144.478-484
  • [4] BISMUTH OXIDE-BASED SOLID ELECTROLYTES FOR FUEL-CELLS
    AZAD, AM
    LAROSE, S
    AKBAR, SA
    [J]. JOURNAL OF MATERIALS SCIENCE, 1994, 29 (16) : 4135 - 4151
  • [5] Thermal, optical and dielectric properties of phase stabilized δ - Dy-Bi2O3 ionic conductors
    Bandyopadhyay, Swagata
    Dutta, Abhigyan
    [J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2017, 102 : 12 - 20
  • [6] Bartonickova Eva., 2007, Processing and Application of Ceramics, V1, P29, DOI 10.2298/PAC0702029B
  • [7] A bismuth oxide nanoplate-based carbon dioxide gas sensor
    Bhande, Sambhaji S.
    Mane, Rajaram S.
    Ghule, Anil V.
    Han, Sung-Hwan
    [J]. SCRIPTA MATERIALIA, 2011, 65 (12) : 1081 - 1084
  • [8] Low-temperature electrodeposition of the high-temperature cubic polymorph of bismuth(III) oxide
    Bohannan, EW
    Jaynes, CC
    Shumsky, MG
    Barton, JK
    Switzer, JA
    [J]. SOLID STATE IONICS, 2000, 131 (1-2) : 97 - 107
  • [9] Solution combustion synthesis of ZnO powders using mixture of fuels in closed system
    Bolaghi, Z. Kalantari
    Hasheminiasari, M.
    Masoudpanah, S. M.
    [J]. CERAMICS INTERNATIONAL, 2018, 44 (11) : 12684 - 12690
  • [10] Processing of hydroxyapatite obtained by combustion synthesis
    Canillas, M.
    Rivero, R.
    Garcia-Carrodeguas, R.
    Barba, F.
    Rodriguez, Miguel A.
    [J]. BOLETIN DE LA SOCIEDAD ESPANOLA DE CERAMICA Y VIDRIO, 2017, 56 (05): : 237 - 242