Ordered micellar and inverse micellar lyotropic phases

被引：52
作者：
Shearman, G. C.
Tyler, A. I. I.
Brooks, N. J.
Templer, R. H.
Ces, O.
Law, R. V.
Seddon, J. M. [1 ]
机构：
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England
来源：
LIQUID CRYSTALS | 2010年 / 37卷 / 6-7期
基金：
英国工程与自然科学研究理事会;
关键词：
amphiphiles; interfacial curvature; soft matter self-assembly; lyotropic liquid crystals; cubic phases; ordered micellar phases; LIPID-CONTAINING SYSTEMS; X-RAY-DIFFRACTION; FRACTURE ELECTRON-MICROSCOPY; CUBIC-PHASE; LIQUID-CRYSTALLINE; BLOCK-COPOLYMER; EPITAXIAL RELATIONSHIPS; DIVALENT SURFACTANTS; WATER-SYSTEMS; TRANSLATIONAL DIFFUSION;
D O I：
10.1080/02678292.2010.484917
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this article we review the ordered micellar and inverse micellar lyotropic liquid-crystalline phases that can be formed by amphiphilic molecules such as lipids and surfactants. We focus first on the self-assembly of amphiphiles into aggregates, and then consider the interfacial curvature and the role of curvature elasticity and packing constraints in determining the allowed structures. We then review the range of ordered micellar and inverse micellar phases that have so far been observed in a variety of surfactant and lipid systems. Finally, we describe certain characteristic properties, such as the epitaxy between phases, and the self-diffusion and electrical conductivity within such ordered micellar phases.
引用
收藏
页码：679 / 694
页数：16
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