Microwave-Assisted, Pd(0)-Catalyzed Cross-Coupling of Diazirines with Aryl Halides

被引：36
作者：
Zhao, Xia [1 ,2 ]
Wu, Guojiao [1 ,2 ]
Yan, Chong [1 ,2 ]
Lu, Kui [1 ,2 ]
Li, Hui [1 ,2 ]
Zhang, Yan [1 ,2 ]
Wang, Jianbo [1 ,2 ,3 ]
机构：
[1] Peking Univ, BNLMS, Minist Educ, Coll Chem, Beijing 100871, Peoples R China
[2] Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Coll Chem, Beijing 100871, Peoples R China
[3] Chinese Acad Sci, State Key Lab Organometoll Chem, Shanghai 200032, Peoples R China
来源：
ORGANIC LETTERS | 2010年 / 12卷 / 23期
关键词：
CATALYZED CARBENE INSERTION; MU-CARBENE; VINYL HALIDES; COMPLEXES; TOSYLHYDRAZONE; DIAZOESTERS; GENERATION; RHODIUM; DESIGN; COBALT;
D O I：
10.1021/ol102434v
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Pd(0)-catalyzed cross-coupling reactions of diazirines with aryl halides under microwave heating conditions afford a series of substituted olefins. A reaction mechanism involving the migratory insertion of the Pd carbene intermediate is proposed.
引用
收藏
页码：5580 / 5583
页数：4
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