Synthesis and structure of [Zn(OMe)(L)]•[Zn(OH)(L)]• 2(BPh4), L = cis,cis-1,3,5-tris[(E,E)-3-(2-furyl) acrylideneamino] cyclohexane:: structural models of carbonic anhydrase and liver alcohol dehydrogenase

被引：42

作者：

Cronin, L ^{[1
]}

Walton, PH ^{[1
]}

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 13期

关键词：

D O I：

10.1039/b302895j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Direct reaction of [Zn(OH)(L)](+), L = cis, cis-1,3,5-tris[(E, E)3-( 2-furyl) acrylideneamino] cyclohexane, with methanol gives a mixture of the starting material and [ Zn(OMe)(L)](+); structural analysis of the complexes shows that they are models of reactive intermediates in the catalytic cycles of the zinc enzymes carbonic anhydrase and liver alcohol dehydrogenase.

引用

页码：1572 / 1573

页数：2

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