Catalytic C-H amination: the stereoselectivity issue

被引：524

作者：

Collet, Florence ^{[1
]}

Lescot, Camille ^{[1
]}

Dauban, Philippe ^{[1
]}

机构：

[1] CNRS, Ctr Rech Gif, Inst Chim Subst Nat, UPR 2301, F-91198 Gif Sur Yvette, France

来源：

CHEMICAL SOCIETY REVIEWS | 2011年 / 40卷 / 04期

关键词：

CHIRAL DIRHODIUM(II) CARBOXYLATES; NITROGEN-ATOM-TRANSFER; SILYL ENOL ETHERS; SULFAMATE ESTERS; ENANTIOSELECTIVE AMINATION; INTRAMOLECULAR AMIDATION; MANGANESE PORPHYRINS; BOND OXIDATION; CHLORAMINE-T; HYDROCARBONS;

D O I：

10.1039/c0cs00095g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic C-H amination has recently emerged as a unique tool for the synthesis of amines. This tutorial review highlights the existing protocols catalyzed by metal complexes (rhodium, copper, ruthenium, manganese and palladium) allowing diastereo- and enantioselective C-H amination. Substrate-, catalyst- and reagent-controlled methodologies are detailed. They involve either catalytic nitrene C-H insertion or C-H activation.

引用

页码：1926 / 1936

页数：11

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