Hydrothermal synthesis and structure of a bi-capped 1D chain (H2en)3H3O[Mo8V4O36(VO4)(VO)2]•4H2O

被引：20
作者：
Luan, GY [1 ]
Wang, EB [1 ]
Han, ZB [1 ]
Li, YG [1 ]
机构：
[1] NE Normal Univ, Dept Chem, Changchun 130024, Jinlin, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 10期
基金：
中国国家自然科学基金;
关键词：
heteropolymolybdovanadates; 1D chain; crystal structure; hydrothermal synthesis;
D O I：
10.1016/S1387-7003(01)00250-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title compound, (H(2)en)(3)H3O[Mo8V4O36(VO4)(VO)(2)]. 4H(2)O, Was hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. The crystal data: monoclinic, P2(1/c), a = 19.804(4) Angstrom, b = 20.634(4) Angstrom, c = 11.920(2) Angstrom, beta = 94.76(3)degrees. X-ray crystallographic study showed that the crystal structure was constructed by bi-capped alpha -Keggin fragment {Mo8C7O42} units linked together by V-O-V bonds to a chain. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：541 / 543
页数：3
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