A tetrameric neodymium silanolate:: [Nd(OSiMe3)3]4

被引：7

作者：

Mansfeld, D ^{[1
]}

Mehring, M ^{[1
]}

机构：

[1] Univ Dortmund, Fachbereich Chem, D-44221 Dortmund, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2005年 / 631卷 / 12期

关键词：

neodymium; bismuth; silanolate; crystal structure;

D O I：

10.1002/zaac.200500263

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound [Nd(OSiMe3)](4) (1) was prepared by reaction of [Nd{N(SiMe3)(2)}(3)] with Me3SiOH in toluene at room temperature. Compound I crystallized from a concentrated toluene solution in the monoclinic space group P2(1)/n with the lattice constants a = 15.144(1) angstrom, b = 25.142(1) angstrom, c = 20.391(1) angstrom and beta = 103.755(2)degrees. In the solid state a tetramer is observed which shows Nd-O bond distances in the range 2.129(2)-2.675(2) angstrom.

引用

页码：2429 / 2432

页数：4

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