Copper(II), cobalt(II), manganese(II) and nickel(II) bis(hexafluoroacetylacetonate) complexes with N-vinylimidazole

被引：10

作者：

Smirnov, Vladimir I. ^{[1
]}

Sinegovskaya, Lidiya M. ^{[1
]}

Parshina, Lidiya N. ^{[1
]}

Artem'ev, Alexander V. ^{[2
,3
]}

Sterkhova, Irina V. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, AE Favorsky Irkutsk Inst Chem, Irkutsk 664033, Russia

[2] Russian Acad Sci, Siberian Branch, AV Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

[3] Novosibirsk State Univ, Novosibirsk 630090, Russia

来源：

MENDELEEV COMMUNICATIONS | 2020年 / 30卷 / 02期

关键词：

metal complexes; hexafluoroacetylacetonates; crystal structure; X-ray; UV-VIS spectra; CRYSTAL-STRUCTURE; METAL-COMPLEXES;

D O I：

10.1016/j.mencom.2020.03.040

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new manganese(II) and nickel(II) bis(hexafluoroacetylacetonate) complexes with N-vinylimidazole were synthesized and characterized by single crystal X-ray diffraction analysis, UV-VIS and IR spectroscopy. Their structures were compared with those of related copper(II) and cobalt(II) complexes. In the case of copper complex, the coordination site formed by hexafluoroacetylacetonate at the Cu2+ ion and nitrogen atoms of the two vinylimidazole cycles is slightly distorted, while in all the other considered complexes, this distortion is insignificant.

引用

页码：246 / 248

页数：3

共 24 条

[1]

[Anonymous], [No title captured]

[2]

[Anonymous], [No title captured]

[3] First heteroleptic diselenophosphinate and thioselenophosphinate nickel(II) complexes with N-donor co-ligands [J].

Artem'ev, Alexander V. ;

Gusarova, Nina K. ;

Bagryanskaya, Irina Yu. ;

Gatilov, Yuriy V. ;

Sutyrina, Anastasiya O. .

POLYHEDRON, 2016, 111 :79-85

[4] Synthesis of metal complexes with 2-[bis(2-phenylethyl)thiophophorylhydroxymethyl]-1-organilimidazoles.: Crystal structure of ZnCl2•2L [J].

Baikalova, L. V. ;

Sokol, V. I. ;

Chipanina, N. N. ;

Ivanova, N. I. ;

Gusarova, N. K. ;

Afonin, A. V. ;

Andreev, P. N. ;

Sergienko, V. S. ;

Trofimov, B. A. .

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2008, 34 (07) :480-492

[5] Crystal and molecular structures of the complexes of cobalt dichloride with 1-isopropenylimidazole and 1-vinylimidazole [J].

Baikalova, L. V. ;

Sokol, V. I. ;

Zyryanova, I. A. ;

Fedyanin, I. V. ;

Khrustalev, V. N. ;

Zel'bst, E. A. ;

Tarasova, O. A. ;

Sergienko, V. S. ;

Trofimov, B. A. .

RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2006, 76 (05) :791-797

[6] Crystal and molecular structure of bis(1-vinylimidazole)diacetatozinc [J].

Baikalova, LV ;

Sokol, VI ;

Khrustalev, VN ;

Zel'bst, EA ;

Trofimov, BA .

RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2005, 75 (09) :1469-1474

[7] A STUDY OF BIS(HEXAFLUOROACETYLACETONATO)COPPER(2) [J].

BERTRAND, JA ;

KAPLAN, RI .

INORGANIC CHEMISTRY, 1966, 5 (03) :489-&

[8] Solution and Solid-State Study of the Spin-Crossover [FeII(R-bik)3](BF4)2 Complexes (R = Me, Et, Vinyl) [J].

De, Siddhartha ;

Tewary, Subrata ;

Garnier, Delphine ;

Li, Yanling ;

Gontard, Geoffrey ;

Lisnard, Laurent ;

Flambard, Alexandrine ;

Breher, Frank ;

Boillot, Marie-Laure ;

Rajaraman, Gopalan ;

Lescouezec, Rodrigue .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018, (3-4) :414-428

[9] Structural and Physical Investigations of Coordination Complexes Involving Pyridylethylenedithio-Tetrathiafulvalene Ligands Decorated with Cyanoethylsulfanyl and Cyano-ethylselanyl Moieties [J].

Douib, Haiet ;

Pointillart, Fabrice ;

Lefeuvre, Bertrand ;

Golhen, Stephane ;

Cador, Olivier ;

Le Guennic, Boris ;

Gouasmia, Abdelkrim ;

Ouahab, Lahcene .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, (36) :5630-5639

[10]

Drago R.S., 1992, PHYS METHODS CHEM, V2nd

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