Synthesis of carbon nitride nanotubes with the C3N4 stoichiometry via a benzene-thermal process at low temperatures

被引:262
作者
Guo, QX
Xie, Y [1 ]
Wang, XJ
Zhang, SY
Hou, T
Lv, SC
机构
[1] Univ Sci & Technol China, Struct Res Lab, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
关键词
D O I
10.1039/b311390f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this communication, we first report the direct synthesis of high-quality carbon nitride nanotubes (CNNTs) with inner diameters of 50-100 nm and wall thicknesses of 20-50 nm with the C3N4 stoichiometry on a high-yield of 40% via a simple benzene-thermal process involving the reaction Of C3N3Cl3 With NaN3 in a Teflon-lined autoclave at 220 degreesC without using any catalyst or template.
引用
收藏
页码:26 / 27
页数:2
相关论文
共 16 条
[1]   Thermodynamic analysis of the formation of carbon nitrides under pressure [J].
Badding, JV ;
Nesting, DC .
CHEMISTRY OF MATERIALS, 1996, 8 (02) :535-540
[2]   BORON-NITRIDE NANOTUBES [J].
CHOPRA, NG ;
LUYKEN, RJ ;
CHERREY, K ;
CRESPI, VH ;
COHEN, ML ;
LOUIE, SG ;
ZETTL, A .
SCIENCE, 1995, 269 (5226) :966-967
[3]   X-ray photoelectron spectroscopy reference data for identification of the C3N4 phase in carbon-nitrogen films [J].
Dementjev, AP ;
de Graaf, A ;
van de Sanden, MCM ;
Maslakov, KI ;
Naumkin, AV ;
Serov, AA .
DIAMOND AND RELATED MATERIALS, 2000, 9 (11) :1904-1907
[4]   Synthesis of nitrogen-rich carbon nitride networks from an energetic molecular azide precursor [J].
Gillan, EG .
CHEMISTRY OF MATERIALS, 2000, 12 (12) :3906-3912
[5]   Single-crystal gallium nitride nanotubes [J].
Goldberger, J ;
He, RR ;
Zhang, YF ;
Lee, SW ;
Yan, HQ ;
Choi, HJ ;
Yang, PD .
NATURE, 2003, 422 (6932) :599-602
[6]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[7]   Powder synthesis and characterization of amorphous carbon nitride [J].
Khabashesku, VN ;
Zimmerman, JL ;
Margrave, JL .
CHEMISTRY OF MATERIALS, 2000, 12 (11) :3264-3270
[8]   PREDICTION OF NEW LOW COMPRESSIBILITY SOLIDS [J].
LIU, AY ;
COHEN, ML .
SCIENCE, 1989, 245 (4920) :841-842
[9]   Large-scale synthesis of carbon nanotubes by an ethanol thermal reduction process [J].
Liu, JW ;
Shao, MW ;
Chen, XY ;
Yu, WC ;
Liu, XM ;
Qian, YT .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (27) :8088-8089
[10]   Relative stability of some possible phases of graphitic carbon nitride [J].
Lowther, JE .
PHYSICAL REVIEW B, 1999, 59 (18) :11683-11686