Square [Pd4(μ-CN)4(C6F5)4(PEt3)4]•2C6H5CH3

被引:5
|
作者
Charmant, JPH
Espinet, P
Soulantica, K
机构
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
[2] Univ Valladolid, Fac Ciencias, Dept Quim Inorgan, E-47005 Valladolid, Spain
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷
关键词
D O I
10.1107/S1600536801014994
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The tetrameric title complex in the crystal of its toluene disolvate, i.e. tetra-mu -cyano-tetrakis[(pentafluorophenyl)(triethylphosphine)palladium(II)] toluene disolvate, [Pd-4 (mu -CN)(4) (C6F5)(4) (PEt3)(4)] . 2C(7)H(8), occupies a special position on a crystallographic inversion centre and contains a square arrangement of four square-planar palladium centres.
引用
收藏
页码:m451 / m453
页数:3
相关论文
共 50 条
  • [31] Activation of C-F and C-H bonds by polyalkylcyclopentadienylrhodium complexes:: crystal structure of [(η5-C5Me4Et)RhCl{(C6F5)2PCH2CH2P(C6F5)2}]+.BF4-
    Atherton, MJ
    Fawcett, J
    Holloway, JH
    Hope, EG
    Martin, SM
    Russell, DR
    Saunders, GC
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 555 (01) : 67 - 79
  • [32] [RU(ETA(5)-C5H5)(ETA(4)-C5H4O)(AS(CH3)(3))]PF6 AND [RU(ETA(5)-C5H5)(ETA(4)-C5H4O)-(AS(C6H5)(3))]PF6
    KIRCHNER, K
    SCHMID, R
    MEREITER, K
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 (pt 3) : 361 - 364
  • [33] Borato-cyclopentadienyl half-sandwich complexes.: Crystal structures of [NEt4][C5H5B(C6F5)3]•CH2Cl2 and [NEt4]2[{C5H4B(C6F5)3}Zr(μ-Cl)Cl2]2
    Lancaster, SJ
    Thornton-Pett, M
    Dawson, DM
    Bochmann, M
    ORGANOMETALLICS, 1998, 17 (18) : 3829 - 3831
  • [34] Five-coordinate fluorobenzothiolate osmium(IV) complexes [Os(SRF)4(PR3)] (RF = C6F4H-4, R3 = Ph2(C6F5); RF = C6F4H-4, R3 = (OPh)3; RF = C6F5, R3 = (OPh)3): Single-crystal structures and solution structural characterization
    Ceron, Margarita
    Cortina, Veronica
    Ramirez-Monroy, Armando
    Bernes, Sylvain
    Torrens, Hugo
    Arroyo, Maribel
    POLYHEDRON, 2011, 30 (07) : 1250 - 1257
  • [35] Monosubstituted Phenylboronic Acids, R–B(OH)2 (R = C6H5, C6H4CH3, C6H4NH2, C6H4OH, and C6H4F): A Computational Investigation
    Niny Z. Rao
    Joseph D. Larkin
    Charles W. Bock
    Structural Chemistry, 2017, 28 : 945 - 955
  • [36] Steric effects in ferrocenylketimines and aldimines. X-ray crystal structures of [(eta(5)-C5H5)Fe{(eta(5)-C5H4)-C(C6H5)=N-R'}], {R'=C6H4-4-CH3 or C6H4-2-CH3}
    Lopez, C
    Bosque, R
    Solans, X
    FontBardia, M
    NEW JOURNAL OF CHEMISTRY, 1996, 20 (12) : 1285 - 1292
  • [37] [C6F5Xe]+ and [C6F5XeNCCH3]+ salts of the weakly coordinating borate anions, [BY4]- (Y = CN, CF3, or C6F5)
    Koppe, Karsten
    Frohn, Hermann-J.
    Mercier, Helene P. A.
    Schrobilgen, Gary J.
    INORGANIC CHEMISTRY, 2008, 47 (08) : 3205 - 3217
  • [38] X-ray diffraction study of p-(alkoxybenzylidene)-p′-toluidines C2H5O-C6H4-CH=N-C6H4-CH3 and C4H9O-C6H4-CH=N-C6H4-CH3
    L. G. Kuz’mina
    N. S. Kucherepa
    M. N. Rodnikova
    Crystallography Reports, 2008, 53 : 1016 - 1022
  • [39] X-Ray Diffraction Study of p-(Alkoxybenzylidene)-p′-Toluidines C2H5O-C6H4-CH=N-C6-H4-CH3 and C4H9O-C6H4-CH=N-C6H4-CH3
    Kuz'mina, L. G.
    Kucherepa, N. S.
    Rodnikova, M. N.
    CRYSTALLOGRAPHY REPORTS, 2008, 53 (06) : 1016 - 1022
  • [40] K2[PD(C6F5)4]-CATALYZED CYCLOTRIMERIZATION OF MALONONITRILE
    LOPEZ, G
    SANCHEZ, G
    GARCIA, G
    GALVEZ, J
    RUIZ, J
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 321 (02) : 273 - 278