Theory of polyelectrolytes in solutions and at surfaces

被引：1277
作者：
Dobrynin, AV [1 ]
Rubinstein, M
机构：
[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA
[2] Univ Connecticut, Polymer Program, Inst Mat Sci, Storrs, CT 06269 USA
[3] Univ Connecticut, Dept Phys, Storrs, CT 06269 USA
来源：
PROGRESS IN POLYMER SCIENCE | 2005年 / 30卷 / 11期
基金：
美国国家科学基金会; 美国国家航空航天局;
关键词：
polyelectrolytes; ion-containing polymers; counterions; distribution of counterions; condensation of counterions; hydrophobic polyclectrolytes; polyelectrolyte solutions; dynamics of polyelectrolytes; rheology of polyclectrolytes; adsorption of charged polymers;
D O I：
10.1016/j.progpolymsci.2005.07.006
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Polyelectrolytes are polymers carrying either positively or negatively charged ionizable groups. The properties of these polymers in solutions and at charged surfaces depend on the fraction of dissociated ionic groups, solvent quality for polymer backbone, solution dielectric constant, salt concentration, and polymer-substrate interactions. In this review, we summarize the current development of theoretical models describing properties of polyelectrolyte solutions and adsorption of charged polymers at surfaces and interfaces. We discuss in detail the conformational properties of polyelectrolyte chains in dilute and semidilute solutions, the phenomenon of counterion condensation, the necklace structure of polyelectrolytes in poor solvent conditions for polymer backbone, the dynamics of polyelectrolyte solutions, the surface overcharging by adsorbed polyelectrolytes and its implication for assembled polyelectrolyte multilayers. (c) 2005 Elsevier Ltd. All rights reserved.
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页码：1049 / 1118
页数：70
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