Dehydration of xylose over sulfated tin oxide catalyst: Influences of the preparation conditions on the structural properties and catalytic performance

被引：75

作者：

Suzuki, Takeshi ^{[1
]}

Yokoi, Toshiyuki ^{[1
]}

Otomo, Ryoichi ^{[1
]}

Kondo, Junko N. ^{[1
]}

Tatsumi, Takashi ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

APPLIED CATALYSIS A-GENERAL | 2011年 / 408卷 / 1-2期

关键词：

Sulfated metal oxides; Tin oxide; Dehydration of xylose; LIQUID-PHASE DEHYDRATION; MEERWEIN-PONNDORF-VERLEY; SOLID ACID CATALYSTS; METAL-OXIDES; ZEOLITE; ISOMERIZATION; TEMPERATURE; ZIRCONIA; BIOMASS; LEWIS;

D O I：

10.1016/j.apcata.2011.09.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Various sulfated metal oxides were tested as solid acid catalyst for the dehydration of xylose to furfural under milder conditions. On the basis of our findings that sulfated tin oxide exhibited the highest catalytic activity, the effects of the content of SO42- group and the calcination temperature on the structural properties and catalytic performance were investigated, and the reusability of the sulfated tin oxide catalyst was evaluated. The acid property on the sulfated tin oxide catalyst was characterized by in situ FT-IR observations of the CO-adsorbed sample. Finally, the reaction mechanism of dehydration of xylose over the SO42-/SnO2 catalyst was considered. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：117 / 124

页数：8

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