A new preparation of Au nanoplates and their application for glucose sensing

被引:82
作者
Zhang, Yingwei [1 ]
Chang, Guohui [1 ]
Liu, Sen [1 ]
Lu, Wenbo [1 ]
Tian, Jingqi [1 ,2 ]
Sun, Xuping [1 ]
机构
[1] Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Jilin, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
关键词
Au nanoplate; Tannic acid; Glucose biosensor; Human blood serum; METAL NANOPARTICLES; ELECTROCHEMICAL BIOSENSORS; SILVER NANOPARTICLES; GOLD NANOPARTICLES; COMPOSITE FILM; REDUCTION; PARTICLES; PLATINUM; SURFACE; OXIDASE;
D O I
10.1016/j.bios.2011.07.041
中图分类号
Q6 [生物物理学];
学科分类号
071011 ;
摘要
The present communication demonstrates a relatively green preparative route toward Au nanoplates in aqueous solution at room temperature with the use of tannic acid (TA), which is an environmentally friendly, soluble polyphenol, as a reducing agent. Such Au nanoplates exhibit notable catalytic performance toward the oxidation and reduction of H(2)O(2). A glucose biosensor was further fabricated by immobilizing glucose oxidase (GOD) into chitosan-Au nanoplate composites film on the surface of glassy carbon electrode (GCE). This sensor exhibits good response to glucose, and the linear response range is estimated to be from 2 to 20 mM (R = 0.999) at 0.65 V and from 2 to 10 mM (R = 0.993) at -0.2 V, respectively. The sensitivity of the sensor determined from the slopes is 49.5 mu A mM(-1) cm(-2) at 0.65 V. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:344 / 348
页数:5
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