ANISOTROPIC COMPRESSION. WHAT CAN IT TEACH US ABOUT INTERMOLECULAR INTERACTIONS?

被引：23

作者：

Boldyreva, Elena ^{[1
]}

机构：

[1] REC 008 Novosibirsk State Univ, Inst Solid State Chem & Mechanochem SB RAS, Novosibirsk 630128, Russia

来源：

HIGH-PRESSURE CRYSTALLOGRAPHY: FROM FUNDAMENTAL PHENOMENA TO TECHNOLOGICAL APPLICATIONS | 2010年

关键词：

Lattice strain; anisotropy; intermolecular interactions; molecular crystals; hydrogen bonds; HIGH-PRESSURE; DIFFRACTION; SOLIDS;

D O I：

10.1007/978-90-481-9258-8_13

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The effect of pressure on solids is often discussed in terms of bulk compressibility. At the same time, for any solids with the crystal structures, the symmetry of which is lower than cubic, it is not sufficient to describe the bulk compressibility alone, since the structural distortion is anisotropic - i.e. depends on the crystallographic direction. The lecture gives a comprehensive introduction into the techniques of studying the strain anisotropy based on diffraction experiments, and illustrates, how the knowledge of the anisotropy of lattice strain may assist in understanding the intermolecular interactions in crystals.

引用

页码：147 / 159

页数：13

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