Alkoxycarbonylation of olefins with carbon dioxide by a reusable heterobimetallic ruthenium-cobalt catalytic system

被引：37

作者：

Zhang, Xuehua ^{[1
,2
,3
]}

Shen, Chaoren ^{[1
]}

Xia, Chungu ^{[1
]}

Tian, Xinxin ^{[4
]}

He, Lin ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys LICP, Suzhou Res Inst, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[3] Yancheng Teachers Univ, Yancheng 224007, Jiangsu, Peoples R China

[4] Shanxi Univ, Inst Mol Sci, Key Lab Mat Energy Convers & Storage Shanxi Prov, Taiyuan 030006, Shanxi, Peoples R China

来源：

GREEN CHEMISTRY | 2018年 / 20卷 / 24期

基金：

中国国家自然科学基金;

关键词：

GAS SHIFT REACTION; CARBONYLATION REACTIONS; METHANOL HOMOLOGATION; ALKYL TOSYLATES; BETA-LACTONES; CO2; HYDROFORMYLATION; METAL; REACTIVITY; CLUSTERS;

D O I：

10.1039/c8gc02289e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The heterobimetallic ruthenium-cobalt catalytic system exhibited good catalytic performance and reusability in the reductive alkoxycarbonylation of olefins with carbon dioxide. Compared to the previous system only consisting of ruthenium catalyst, the binary catalyst system effectively reduced the usage of noble metal and ionic liquid additives. The respective contribution of ruthenium and cobalt catalysts in this multiple-step catalytic process was investigated by a series of condition-controlled experiments. The evolution of the ruthenium catalyst and the occurrence of alkene hydrogenation during the reaction was explained by theortical calculations.

引用

页码：5533 / 5539

页数：7

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