Preparation of styrene-divinyl benzene copolymer-supported platinum complexes and their catalytic properties in hydrosilylation

被引：0
|
作者：
Kan, CY [1 ]
Yuan, Q [1 ]
Luo, AG [1 ]
Kong, XZ [1 ]
机构：
[1] SHANDONG UNIV,DEPT CHEM,JINAN 250100,PEOPLES R CHINA
来源：
POLYMERS FOR ADVANCED TECHNOLOGIES | 1996年 / 7卷 / 02期
关键词：
polymer-supported platinum catalyst; hydrosilylation; dichloromethylsilane; unsaturated monomer;
D O I：
10.1002/(SICI)1099-1581(199602)7:2<76::AID-PAT451>3.0.CO;2-0
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A new type of catalyst for the hydrosilylation of unsaturated monomers with dichloromethylsilane (DCMS) was prepared, which consisted of thiolmethylene-substituted styrene-divinyl benzene copolymer and platinum. When using DCMS as a hydrosilylation agent, these catalysts showed a high activity in the hydrosilylation of vinyl and acetylene monomers as styrene, alkyl vinyl silanes, acetylene, phenyl acetylene, butyl acrylate. The activities of catalysts were not significantly reduced even after 20 reuse cycles.
引用
收藏
页码：76 / 78
页数：3
相关论文
共 50 条
  • [31] PREPARATION OF PTHY CATALYSTS - INFLUENCE ON THE CATALYTIC PROPERTIES OF THE COMPLEXES USED AS PLATINUM PRECURSORS
    GUERIN, M
    KAPPENSTEIN, C
    ALVAREZ, F
    GIANNETTO, G
    GUISNET, M
    APPLIED CATALYSIS, 1988, 45 (02): : 325 - 333
  • [32] PREPARATION, CHARACTERIZATION AND CATALYTIC PROPERTIES OF CARBON-SUPPORTED PLATINUM ZIRCONIUM ALLOY CATALYSTS
    SZYMANSKI, R
    CHARCOSSET, H
    JOURNAL OF MOLECULAR CATALYSIS, 1984, 25 (1-3): : 337 - 345
  • [33] PREPARATION AND PROPERTIES OF MACRORETICULAR CHELATING RESINS CONTAINING AMIDOXIME GROUPS FROM STYRENE-(DIVINYL-TYPE COMPOUND) COPOLYMER BEADS
    EGAWA, H
    NONAKA, T
    NONAKA, H
    NIPPON KAGAKU KAISHI, 1993, (06) : 752 - 760
  • [34] Synthesis of a series of new platinum organometallic complexes derived from bidentate Schiff-base ligands and their catalytic activity in the hydrosilylation and dehydrosilylation of styrene
    Lachachi, M. Belhadj
    Benabdallah, Tayeb
    Aguiar, Pedro M.
    Youcef, M. Hadj
    Whitwood, Adrian C.
    Lynam, Jason M.
    DALTON TRANSACTIONS, 2015, 44 (26) : 11919 - 11928
  • [35] Catalytic oxidation of NO over TiO2 supported platinum clusters I. Preparation, characterization and catalytic properties
    Li, Landong
    Shen, Qun
    Cheng, Jie
    Hao, Zhengping
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2010, 93 (3-4) : 259 - 266
  • [36] Preparation of platinum compositions supported on reduced graphite oxide and their catalytic properties in liquid-phase hydrogenation
    Kushch, S. D.
    Kuyunko, N. S.
    Dremova, N. N.
    Korshunova, L. A.
    KINETICS AND CATALYSIS, 2015, 56 (05) : 584 - 590
  • [37] Preparation of platinum compositions supported on reduced graphite oxide and their catalytic properties in liquid-phase hydrogenation
    S. D. Kushch
    N. S. Kuyunko
    N. N. Dremova
    L. A. Korshunova
    Kinetics and Catalysis, 2015, 56 : 584 - 590
  • [38] Preparation of platinum nanoparticles supported on bayberry tannin grafted silica bead and its catalytic properties in hydrogenation
    Huang, Xin
    Li, Li
    Liao, Xuepin
    Shi, Bi
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2010, 320 (1-2) : 40 - 46
  • [39] SELECTIVE HYDROGENATION OF BENZENE OVER PLATINUM OR PALLADIUM SUPPORTED ON ORGANIC POLYMERS CATALYSTS .1. PREPARATION AND CATALYTIC PROPERTIES OF PALLADIUM DEPOSITED ON POLYAMIDE-6-6
    MICHEL, C
    HOANGVAN, C
    TEICHNER, SJ
    JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1978, 75 (09) : 819 - 825
  • [40] Pre-prepared platinum nanoparticles supported on SBA-15 – preparation, pretreatment conditions and catalytic properties
    Zoltan Kónya
    Eva Molnar
    G. Tasi
    Krisztian Niesz
    Gabor A. Somorjai
    Imre Kiricsi
    Catalysis Letters, 2007, 113 : 19 - 28
12345